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@ARTICLE{Vak:639988,
author = {Vařák, Petr and Jarý, Vítězslav and Babin, Vladimir
and Ševčík, Vojtěch and Volf, Jakub and Nekvindová,
Pavla},
title = {{RE}-doped zinc-silicate glass-ceramics ({RE} = {H}o, {T}m,
{Y}b) based on {Z}n$_2${S}i{O}$_4$ with enhanced photo- and
radioluminescence properties},
journal = {Optical materials},
volume = {169},
issn = {0925-3467},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PUBDB-2025-04691},
pages = {117698},
year = {2026},
note = {Waiting for fulltext},
abstract = {The photoluminescence and radioluminescence investigation
of zinc-silicate glass-ceramics doped with Ho3+ or Tm3+
ions, co-doped with Yb3+ ions, and containing Zn2SiO4
(willemite) crystalline phase are presented. The precursor
glasses were prepared by traditional melt-quenching, the
glass-ceramics were prepared by controlled heat treatment of
the glass. The structure of the resulting glass-ceramics was
determined by X-Ray Diffraction and Transmission Electron
Microscopy, which confirmed the crystallization of Zn2SiO4.
The glass-ceramics were analyzed with respect to the
photoluminescence properties of Tm3+ and Ho3+ ions. The
glass exhibited typical emissions around 2 μm stemming from
the Ho3+ or Tm3+ ions, and the intensity of the emission was
increased by up to 350 $\%$ for Ho3+/Yb3+ and 280 $\%$ for
or Tm3+/Yb3+ by the crystallization. The virgin glasses
exhibited longest values of lifetime of 1.596 ms for
Ho3+/Yb3+-doped samples, and 0.877 ms for Tm3+/Yb3+-doped
samples. The crystallization of Zn2SiO4 crystalline phase
resulted in radioluminescence around 350 nm after the X-ray
excitation. The radioluminescence lifetime of samples
containing Zn2SiO4 was approximately 30 ns. Although no
obvious interaction between the rare earth ions and Zn2SiO4
was observed, the very fast response makes the materials an
interesting choice for scintillation devices.},
cin = {DOOR ; HAS-User},
ddc = {670},
cid = {I:(DE-H253)HAS-User-20120731},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20211395
EC (I-20211395-EC)},
pid = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20211395-EC},
experiment = {EXP:(DE-H253)P-P66-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1016/j.optmat.2025.117698},
url = {https://bib-pubdb1.desy.de/record/639988},
}