000639636 001__ 639636
000639636 005__ 20251119161938.0
000639636 0247_ $$2doi$$a10.1002/smll.202505895
000639636 0247_ $$2ISSN$$a1613-6810
000639636 0247_ $$2ISSN$$a1613-6829
000639636 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-04593
000639636 0247_ $$2altmetric$$aaltmetric:182290957
000639636 0247_ $$2pmid$$apmid:40831314
000639636 0247_ $$2openalex$$aopenalex:W4413358836
000639636 037__ $$aPUBDB-2025-04593
000639636 041__ $$aEnglish
000639636 082__ $$a620
000639636 1001_ $$0P:(DE-H253)PIP1086580$$aBuyan-Arivjikh, Altantulga$$b0
000639636 245__ $$aCsPbBr$_3$ Nanocrystals as Bottom Interface Nucleation Seeds for Printing Oriented FAPbI$_3$ Thin Films: An In Situ Study
000639636 260__ $$aWeinheim$$bWiley-VCH$$c2025
000639636 3367_ $$2DRIVER$$aarticle
000639636 3367_ $$2DataCite$$aOutput Types/Journal article
000639636 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1761823324_1454609
000639636 3367_ $$2BibTeX$$aARTICLE
000639636 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000639636 3367_ $$00$$2EndNote$$aJournal Article
000639636 520__ $$aThe exceptional optoelectronic properties of lead halide perovskites are highly sensitive to processing conditions, as uncontrolled crystallization driven by random nucleation often results in defect-rich active layers that impair device performance. Achieving controlled and oriented crystallization in printed films remains a major challenge. To address this, we introduce a pre-deposited CsPbBr3 nanocrystal seed layer at the bottom interface to guide crystallization and suppress defect formation. This strategy is evaluated via an in situ study on FAPbI3, offering mechanistic insights into the influence of seeding on film growth and optoelectronic quality. Using in situ grazing-incidence wide-angle X-ray scattering, transmission-mode UV–vis absorption, and photoluminescence spectroscopy, phase evolution and seed-mediated growth kinetics are tracked. Seeding accelerates the transition from the photoinactive δ-phase to the photoactive α-phase, yielding a crystallization rate constant over six times higher than in unseeded films. Moreover, the seed layer governs the crystallographic orientation of the resulting perovskite film, leading to improved optical absorption and reduced defect density.
000639636 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x0
000639636 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x1
000639636 536__ $$0G:(GEPRIS)390776260$$aDFG project G:(GEPRIS)390776260 - EXC 2089: e-conversion (390776260)$$c390776260$$x2
000639636 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000639636 693__ $$0EXP:(DE-H253)P-P03-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P03-20150101$$aPETRA III$$fPETRA Beamline P03$$x0
000639636 7001_ $$aFricker, Jascha$$b1
000639636 7001_ $$0P:(DE-H253)PIP1106392$$aBaier, Thomas$$b2
000639636 7001_ $$0P:(DE-H253)PIP1109311$$aCi, Xiaojing$$b3
000639636 7001_ $$0P:(DE-H253)PIP1111579$$aLi, Lixing$$b4
000639636 7001_ $$aGaur, Deepika$$b5
000639636 7001_ $$aPolavarapu, Lakshminarayana$$b6
000639636 7001_ $$0P:(DE-H253)PIP1010504$$aSchwartzkopf, Matthias$$b7
000639636 7001_ $$0P:(DE-HGF)0$$aVayalil, Sarathlal Koyilot$$b8
000639636 7001_ $$0P:(DE-H253)PIP1007825$$aMüller-Buschbaum, Peter$$b9$$eCorresponding author
000639636 773__ $$0PERI:(DE-600)2168935-0$$a10.1002/smll.202505895$$gVol. 21, no. 39, p. e05895$$n39$$pe05895$$tSmall$$v21$$x1613-6810$$y2025
000639636 8564_ $$uhttps://bib-pubdb1.desy.de/record/639636/files/Small%20-%202025%20-%20Buyan%E2%80%90Arivjikh%20-%20CsPbBr3%20Nanocrystals%20as%20Bottom%20Interface%20Nucleation%20Seeds%20for%20Printing%20Oriented%20FAPbI3%20Thin.pdf$$yOpenAccess
000639636 8564_ $$uhttps://bib-pubdb1.desy.de/record/639636/files/Small%20-%202025%20-%20Buyan%E2%80%90Arivjikh%20-%20CsPbBr3%20Nanocrystals%20as%20Bottom%20Interface%20Nucleation%20Seeds%20for%20Printing%20Oriented%20FAPbI3%20Thin.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000639636 909CO $$ooai:bib-pubdb1.desy.de:639636$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000639636 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1086580$$aExternal Institute$$b0$$kExtern
000639636 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1106392$$aExternal Institute$$b2$$kExtern
000639636 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1109311$$aExternal Institute$$b3$$kExtern
000639636 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1111579$$aExternal Institute$$b4$$kExtern
000639636 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1010504$$aDeutsches Elektronen-Synchrotron$$b7$$kDESY
000639636 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1007825$$aExternal Institute$$b9$$kExtern
000639636 9131_ $$0G:(DE-HGF)POF4-632$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vMaterials – Quantum, Complex and Functional Materials$$x0
000639636 9131_ $$0G:(DE-HGF)POF4-6G3$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vPETRA III (DESY)$$x1
000639636 9141_ $$y2025
000639636 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2024-12-27
000639636 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000639636 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bSMALL : 2022$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2024-12-27$$wger
000639636 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)9910$$2StatID$$aIF >= 10$$bSMALL : 2022$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000639636 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-12-27
000639636 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2024-12-27
000639636 9201_ $$0I:(DE-H253)FS-PETRA-D-20210408$$kFS-PETRA-D$$lPETRA-D$$x0
000639636 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x1
000639636 980__ $$ajournal
000639636 980__ $$aVDB
000639636 980__ $$aUNRESTRICTED
000639636 980__ $$aI:(DE-H253)FS-PETRA-D-20210408
000639636 980__ $$aI:(DE-H253)HAS-User-20120731
000639636 9801_ $$aFullTexts