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@ARTICLE{Cherevotan:639633,
      author       = {Cherevotan, Arjun and Singh, Ashutosh Kumar and Yadav,
                      Anish and Maligal-Ganesh, Raghu V. and Raj, Jithu and
                      Pulparambil, Anu and Goud, Devender and Vinod, Chathakudath
                      P. and Peter, Sebastian C.},
      title        = {{M}etal deficiency tuned charge transfer in intermetallic
                      {N}i$_{2−x}${S}n (x = 0.37–0.65) enhances selective
                      conversion of furfural to furfuryl alcohol towards the
                      theoretical limit},
      journal      = {Journal of materials chemistry / A},
      volume       = {13},
      number       = {8},
      issn         = {2050-7488},
      address      = {London ˜[u.a.]œ},
      publisher    = {RSC},
      reportid     = {PUBDB-2025-04590},
      pages        = {6042 - 6048},
      year         = {2025},
      note         = {Waiting for fulltext},
      abstract     = {Heterogeneous catalysis facilitated by intermetallic
                      nanoparticles has recently been the subject of increased
                      scrutiny, given the enhanced selectivity and stability they
                      bestow on many chemical reactions compared to their
                      monometallic components. This paper explores a series of
                      Ni–Sn (Ni$_{2−x}$Sn, where x = 0.65, 0.5, 0.37)
                      intermetallic compounds supported on a high-surface-area
                      support, SBA-15, as catalysts for the selective
                      hydrogenation of furfural to furfuryl alcohol. Rietveld
                      refinements of the X-ray diffraction data show catalysts
                      with mixed intermetallic phases that assist in the
                      catalysis. At the same time, X-ray photoelectron
                      spectroscopy (XPS) studies and X-ray absorption studies
                      indicate the role played by charge transfer from Sn to Ni
                      for the catalysis. Selectivity to the desired furfuryl
                      alcohol in all the intermetallic samples was high (>97\%),
                      but Ni1.35Sn had a relatively lower conversion than the
                      other intermetallic compounds.},
      cin          = {DOOR ; HAS-User},
      ddc          = {530},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / INDIA-DESY - INDIA-DESY
                      Collaboration $(2020_Join2-INDIA-DESY)$},
      pid          = {G:(DE-HGF)POF4-6G3 / $G:(DE-HGF)2020_Join2-INDIA-DESY$},
      experiment   = {EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1039/D4TA06383J},
      url          = {https://bib-pubdb1.desy.de/record/639633},
}