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@ARTICLE{Mukherjee:639591,
author = {Mukherjee, S. and Pal, A. and Tuzi, F. and Polimeni, A. and
Yen, T. W. and Ivashko, O. and Majumdar, Subham and Kumar,
A. and Giri, S.},
title = {{S}uccessive ferroelectric orders and magnetoelectric
coupling without long-range magnetic order in highly
frustrated pyrochlore compounds:
{S}m$_2${T}i$_{2−x}${V}$_x${O}$_7$},
journal = {Physical review / B},
volume = {112},
number = {5},
issn = {2469-9950},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {PUBDB-2025-04567},
pages = {054434},
year = {2025},
abstract = {Sm$_2$Ti$_{2−x}$V$_x$O$_7$, a member of the rare-earth
titanate pyrochlores, exhibits dipolar-octupolar
antiferromagnetism below 𝑇$_𝑁$=0.35K. We observed two
ferroelectric transitions at 182 (𝑇$_{FE1}$) and 52 K
(𝑇$_{FE2}$), significantly higher than 𝑇$_𝑁$ for
Sm$_2$Ti$_{2−𝑥}$V$_𝑥$O$_7$ (𝑥=0,0.1).
Although the ferroelectric transition temperatures remain
unchanged, the polarization value decreases with V doping. A
structural transition to a polar 𝑅3𝑚
rhombohedral phase from the cubic
𝐹𝑑$\bar{3}$𝑚 structure occurs at 𝑇$_{FE1}$
for the pristine compound, involving a distortion in the
pyrochlore lattices formed by the Sm atoms. Remarkably,
linear magnetoelectric coupling is observed in both
compounds, with further enhancement of magnetoelectric (ME)
coupling due to magnetic V doping. The existence of
magnetoelectric coupling without long-range magnetic order
is of fundamental interest for advancing the understanding
and development of ME coupling.},
cin = {DOOR ; HAS-User / FS-PETRA-D},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PETRA-D-20210408},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
INDIA-DESY - INDIA-DESY Collaboration
$(2020_Join2-INDIA-DESY)$},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
$G:(DE-HGF)2020_Join2-INDIA-DESY$},
experiment = {EXP:(DE-H253)P-P21.1-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1103/c2zb-17n9},
url = {https://bib-pubdb1.desy.de/record/639591},
}