% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Davies:639432,
      author       = {Davies, Bernadette and Garcia-Martinez, Fernando and
                      Goodwin, Christopher M. and Degerman, David and Soldemo,
                      Markus and Lömker, Patrick and Grigorev, Vladimir and Bibi,
                      Sara Boscolo and Ali-Löytty, Harri and Engel, Robin Y. and
                      Stenlid, Joakim Halldin and Rodrigues, Gabriel L. S. and
                      Hansson, Tony and Schlueter, Christoph and Zou, Xiaodong and
                      Nilsson, Anders and Koroidov, Sergey},
      title        = {{I}nsight into the {C}arbon {M}onoxide {R}eduction
                      {R}eaction on {C}u(111) from {O}perando {E}lectrochemical
                      {X}‐ray {P}hotoelectron {S}pectroscopy},
      journal      = {Angewandte Chemie / International edition},
      volume       = {64},
      number       = {33},
      issn         = {1433-7851},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2025-04524},
      pages        = {e202506402},
      year         = {2025},
      abstract     = {In this work, we introduce a modified dip-and-pull
                      electrochemical X-ray photoelectron spectroscopy (ECXPS)
                      approach that offers new mechanistic insight into the
                      alkaline carbon monoxide reduction reaction (CORR) over a
                      Cu(111) single crystal surface. We tackle two major
                      unresolved questions in the CORR mechanism that persist in
                      the literature. Firstly, we address the mechanism for
                      methane formation on Cu(111) and show that the mechanism
                      likely proceeds via atomic carbon, which subsequently
                      couples, leading to the accumulation of amorphous carbon on
                      the surface. Secondly, we provide insight into whether the
                      mechanism for acetate formation occurs entirely on the
                      surface or partially within the solution phase, showing that
                      acetate is present on the surface, indicating a
                      surface-based reaction. These insights into surface-based
                      mechanisms provide a handle for designing future catalysts
                      that can efficiently target the binding of specific
                      intermediates. Furthermore, we expect that our modified
                      approach to dip-and-pull ECXPS – in which we have changed
                      the electrode geometry, the method of introducing the
                      reactant gas and used hard x-rays – will significantly
                      expand the technique's applicability, enabling studies of
                      the CO($_2$)RR and beyond.},
      cin          = {DOOR ; HAS-User / FS-PETRA-S},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PETRA-S-20210408},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: II-20211048 EC (II-20211048-EC) / FS-Proposal:
                      I-20230516 EC (I-20230516-EC) / FS-Proposal: I-20221301 EC
                      (I-20221301-EC) / SWEDEN-DESY - SWEDEN-DESY Collaboration
                      $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)II-20211048-EC / G:(DE-H253)I-20230516-EC /
                      G:(DE-H253)I-20221301-EC /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P22-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1002/anie.202506402},
      url          = {https://bib-pubdb1.desy.de/record/639432},
}