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000638830 1001_ $$00000-0003-1325-7238$$aRodríguez-Camargo, Andrés$$b0
000638830 245__ $$aCyclopalladation of a covalent organic framework for near-infrared-light-driven photocatalytic hydrogen peroxide production
000638830 260__ $$aLondon$$bNature Publishing Group UK$$c2025
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000638830 520__ $$aCovalent organic frameworks (COFs) have been developed as photosensitizers for photocatalytic energy conversion over the past decade; however, COF photocatalysts have yet to demonstrate the ability to harvest near-infrared light (above 760 nm, approximately 53% of the solar spectrum) for fuel or chemical conversion. In this work we introduce a post-synthetic functionalization strategy for COFs by incorporating a palladacycle directly into the COF backbone, extending the light absorption of an azobenzene-based COF into the near-infrared region. This approach enables homogeneous, atomically distributed palladium functionalization with a high loading of 12 wt% and without noticeable formation of palladium nanoparticles. The cyclopalladated COF, TpAzo-CPd, was used as a catalyst for photocatalytic hydrogen peroxide production under 810 nm illumination. This study demonstrates the use of COFs for near-infrared photocatalysis and opens the door to palladium-single-site COF catalysts for a wide range of chemical transformations.
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000638830 7001_ $$0P:(DE-H253)PIP1086870$$aTerban, Maxwell W.$$b1
000638830 7001_ $$00009-0003-2209-4458$$aPaetsch, Martina$$b2
000638830 7001_ $$aRico, Elio A.$$b3
000638830 7001_ $$00000-0002-7640-4162$$aGraf, Daniel$$b4
000638830 7001_ $$aHirpara, Radhika$$b5
000638830 7001_ $$00000-0003-2952-816X$$aDuppel, Viola$$b6
000638830 7001_ $$aMoudrakovski, Igor$$b7
000638830 7001_ $$0P:(DE-H253)PIP1018552$$aEtter, Martin$$b8
000638830 7001_ $$00000-0002-3277-8816$$aGuijarro, Néstor$$b9
000638830 7001_ $$aOchsenfeld, Christian$$b10
000638830 7001_ $$0P:(DE-H253)PIP1018079$$aDinnebier, Robert E.$$b11
000638830 7001_ $$0P:(DE-HGF)0$$aYao, Liang$$b12$$eCorresponding author
000638830 7001_ $$00000-0002-3094-303X$$aLotsch, Bettina V.$$b13$$eCorresponding author
000638830 773__ $$0PERI:(DE-600)3105490-0$$a10.1038/s44160-024-00731-1$$gVol. 4, no. 6, p. 710 - 719$$n6$$p710 - 719$$tNature Synthesis$$v4$$x2731-0582$$y2025
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