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@ARTICLE{Bartolom:638813,
author = {Bartolomé, Luis and Verziaggi, Nicola and Brinker, Manuel
and Amayuelas, Eder and Merchori, Sebastiano and Arkan,
Mesude Z. and Eglītis, Raivis and Šutka, Andris and
Chorążewski, Mirosław and Huber, Patrick and Meloni,
Simone and Grosu, Yaroslav},
title = {{T}riboelectrification during non-wetting liquids
intrusion–extrusion in hydrophobic nanoporous silicon
monoliths},
journal = {Nano energy},
volume = {146},
issn = {2211-2855},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {PUBDB-2025-04213},
pages = {111488},
year = {2025},
note = {eutsche Forschungsgemeinschaft (DFG, German Research
Foundation) as part of the Excellence Strategy of the
Federal Government and the federal states – EXC 3120/1 –
533771286},
abstract = {Triboelectric nanogenerators (TENGs) have emerged as
promising devices for converting mechanical energy
intoelectrical energy through contact electrification and
electrostatic induction. However, the generated
energy,unlike instantaneous power, current and voltage, is
rarely addressed in the vibrant research field of TENGs.
Inthis study, we investigate Intrusion–Extrusion
Triboelectric Nanogenerators (IE-TENGs) based on
nanoporoussilicon monoliths and non-wetting liquids (i.e.,
water and a 1 mg/mL polyethylenimine solution), addressing
theenergy generated during this process, conversion
efficiency as well as the mechanism underlying the
observedphenomena. Compared to powder-based IE-TENGs, the
use of monolithic silicon structures enables more
efficientand reproducible energy harvesting, with
significant improvements in both instantaneous power density
andenergy per cycle. We also analyzed the impact of
compression rate and liquid properties on electrical
output,showing that higher compression rates improve power
generation, while modifying the liquid medium signifi-cantly
improves conversion efficiency, reaching up to 9 $\%.$
Furthermore, through computational analysis, weidentify the
crucial role of grafting defects on the generated
triboelectric output. This work introduces a novelapproach
to triboelectric energy harvesting by implementing a
monolithic nanoporous architecture and offeringan
alternative pathway for enhancing contact electrification
via confined solid–liquid interfaces. These
findingsprovide new insights into the triboelectric behavior
of porous systems and pave the way for next-generation
high-performance IE-TENGs, with potential applications in
wearable electronics, environmental energy harvesting,and
self-powered sensing systems.},
cin = {CIMMS},
ddc = {660},
cid = {I:(DE-H253)CIMMS-20211022},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / EHAWEDRY - Energy harvesting via
wetting/drying cycles with nanoporous electrodes (964524) /
Electro-Intrusion - Simultaneous transformation of ambient
heat and undesired vibrations into electricity via
nanotriboelectrification during non-wetting liquid
intrusion-extrusion into-from nanopores (101017858)},
pid = {G:(DE-HGF)POF4-632 / G:(EU-Grant)964524 /
G:(EU-Grant)101017858},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
doi = {10.1016/j.nanoen.2025.111488},
url = {https://bib-pubdb1.desy.de/record/638813},
}