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@ARTICLE{KOC:638431,
author = {KOC, Oemer and Thomas, Rhys and Jenkins, B. and Hofer, C.
and Hegedues, Zoltan and Lienert, Ulrich and Harrison, R. W.
and Preuss, Michael and Ungar, Tamas and Frankel, Philipp},
title = {{T}he effect of proton irradiation dose rate on the
evolution of microstructure in {Z}r alloys: {A} synchrotron
microbeam {X}-ray, {TEM}, and {APT} study},
journal = {Journal of nuclear materials},
volume = {608},
issn = {0022-3115},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PUBDB-2025-04059},
pages = {155721 -},
year = {2025},
note = {Open access},
abstract = {Protons are increasingly used as a surrogate for neutrons
to study radiation damage of engineering alloys used in the
core of a nuclear reactor, enabling high fluences in
comparatively short times. However, the accelerated damage
rate of protons is usually compensated by an increased
irradiation temperature to assist diffusion. To better
understand dose rate effects on microstructure evolution
during radiation damage, recrystallized Low-Sn ZIRLO and
Zircaloy-2 were proton-irradiated to 0.15 dpa at 320 °C
using nominal dose rates of 1.3, 2.5, and 5.2 × 10−5
dpa/s. Depth profiling using microbeam synchrotron XRD was
conducted across the 30 µm deep irradiated regions for line
profile analysis, enabling dislocation line density
determination. We found no significant difference in
dislocation density among the different dose rates for
Zircaloy-2 while Low-Sn ZIRLO displayed dose rate sensitive
microstructural evolution. However, Low-Sn ZIRLO exhibited a
significantly lower overall dislocation density compared to
Zircaloy-2 samples at all dose rates. (S)TEM analysis of the
samples showed clear 〈a〉 loop alignment in Zircaloy-2,
while this was less pronounced in Low-Sn ZIRLO. APT analysis
conducted on Low-Sn ZIRLO specimens showed the early onset
of irradiation induced nanoclusters of Nb, where the
clusters were observed to be comparatively smaller in the
sample exposed to high dose rate irradiation. Overall, the
integration of different techniques has provided a more
comprehensive understanding of the early-stage damage
evolution under differing damage accumulation rates.},
cin = {FS-PETRA-D / DOOR ; HAS-User},
ddc = {620},
cid = {I:(DE-H253)FS-PETRA-D-20210408 /
I:(DE-H253)HAS-User-20120731},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3},
experiment = {EXP:(DE-H253)P-P21.2-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1016/j.jnucmat.2025.155721},
url = {https://bib-pubdb1.desy.de/record/638431},
}