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| 001 | 637980 | ||
| 005 | 20251005055305.0 | ||
| 024 | 7 | _ | |a 10.1038/s41467-025-63768-6 |2 doi |
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| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 500 |
| 100 | 1 | _ | |a Yang, Ye |0 P:(DE-H253)PIP1102554 |b 0 |
| 245 | _ | _ | |a On-liquid surface synthesis of diyne-linked two-dimensional polymer crystals |
| 260 | _ | _ | |a [London] |c 2025 |b Springer Nature |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1759154798_1690395 |2 PUB:(DE-HGF) |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a The synthesis of thin crystalline two-dimensional polymers (2DPs) typically relies on reversible dynamic covalent reactions. While substantial progress has been made in solution-based and interfacial syntheses, achieving 2DPs through irreversible carbon-carbon coupling reactions remains a formidable challenge. Herein, we present an on-liquid surface (a mixture of N,N-dimethylacetamide and water, DMAc-H$_2$O) synthesis method for constructing diyne-linked 2DP (DY$_2$DP) crystals via Glaser coupling, assisted by a perfluoro-surfactant (PFS) monolayer. In-situ spectroscopic and diffraction techniques reveal that the well-ordered PFS monolayer facilitates the accumulation of Cu$^+$ ions and subsequent vertical coupling of acetylenic monomers on the DMAc-H$_2$O surface. Building on these findings, we successfully synthesized micro-scale rod-shaped DY$_2$DP-Por or graphdiyne (GDY) crystals through the polymerization of porphyrin- or benzene-based monomers, respectively. Our study represents a significant advancement in the field of on-liquid surface chemistry and opens up enormous opportunities for constructing C—C bond linked 2DP crystals with unique functionalities. |
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| 536 | _ | _ | |a FC2DMOF - Development of Functional Conjugated Two-Dimensional Metal-Organic Frameworks (852909) |0 G:(EU-Grant)852909 |c 852909 |f ERC-2019-STG |x 3 |
| 536 | _ | _ | |a T2DCP - Development of Thiophene Based Conjugated Polymers in Two Dimensions (819698) |0 G:(EU-Grant)819698 |c 819698 |f ERC-2018-COG |x 4 |
| 536 | _ | _ | |a DFG project G:(GEPRIS)426572620 - Synthese von kristallinen, supramolekularen Polyanilinschichten/2D-Polyanilinen und deren Strukturbestimmung mittels Elektronenbeugung und TEM-Bildgebung (426572620) |0 G:(GEPRIS)426572620 |c 426572620 |x 5 |
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| 536 | _ | _ | |a DFG project G:(GEPRIS)417590517 - SFB 1415: Chemie der synthetischen zweidimensionalen Materialien (417590517) |0 G:(GEPRIS)417590517 |c 417590517 |x 7 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
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| 700 | 1 | _ | |a Wu, Yufeng |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Liu, Chang |0 P:(DE-H253)PIP1028775 |b 2 |
| 700 | 1 | _ | |a Hambsch, Mike |0 P:(DE-H253)PIP1081764 |b 3 |
| 700 | 1 | _ | |a Dong, Tiange |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Bodesheim, David |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Prasad, Mahabir |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Dianat, Arezoo |0 P:(DE-HGF)0 |b 7 |
| 700 | 1 | _ | |a Kühne, Thomas D. |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Cuniberti, Gianaurelio |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Mannsfeld, Stefan |0 P:(DE-H253)PIP1029114 |b 10 |
| 700 | 1 | _ | |a Parkin, Stuart S. P. |0 P:(DE-HGF)0 |b 11 |
| 700 | 1 | _ | |a Dong, Renhao |0 P:(DE-HGF)0 |b 12 |
| 700 | 1 | _ | |a Wang, Zhiyong |0 P:(DE-H253)PIP1102541 |b 13 |e Corresponding author |
| 700 | 1 | _ | |a Feng, Xinliang |0 P:(DE-H253)PIP1081776 |b 14 |e Corresponding author |
| 773 | _ | _ | |a 10.1038/s41467-025-63768-6 |g Vol. 16, no. 1, p. 8243 |0 PERI:(DE-600)2553671-0 |n 1 |p 8243 |t Nature Communications |v 16 |y 2025 |x 2041-1723 |
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