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@ARTICLE{Yang:637980,
      author       = {Yang, Ye and Wu, Yufeng and Liu, Chang and Hambsch, Mike
                      and Dong, Tiange and Bodesheim, David and Prasad, Mahabir
                      and Dianat, Arezoo and Kühne, Thomas D. and Cuniberti,
                      Gianaurelio and Mannsfeld, Stefan and Parkin, Stuart S. P.
                      and Dong, Renhao and Wang, Zhiyong and Feng, Xinliang},
      title        = {{O}n-liquid surface synthesis of diyne-linked
                      two-dimensional polymer crystals},
      journal      = {Nature Communications},
      volume       = {16},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Springer Nature},
      reportid     = {PUBDB-2025-03949},
      pages        = {8243},
      year         = {2025},
      abstract     = {The synthesis of thin crystalline two-dimensional polymers
                      (2DPs) typically relies on reversible dynamic covalent
                      reactions. While substantial progress has been made in
                      solution-based and interfacial syntheses, achieving 2DPs
                      through irreversible carbon-carbon coupling reactions
                      remains a formidable challenge. Herein, we present an
                      on-liquid surface (a mixture of N,N-dimethylacetamide and
                      water, DMAc-H$_2$O) synthesis method for constructing
                      diyne-linked 2DP (DY$_2$DP) crystals via Glaser coupling,
                      assisted by a perfluoro-surfactant (PFS) monolayer. In-situ
                      spectroscopic and diffraction techniques reveal that the
                      well-ordered PFS monolayer facilitates the accumulation of
                      Cu$^+$ ions and subsequent vertical coupling of acetylenic
                      monomers on the DMAc-H$_2$O surface. Building on these
                      findings, we successfully synthesized micro-scale rod-shaped
                      DY$_2$DP-Por or graphdiyne (GDY) crystals through the
                      polymerization of porphyrin- or benzene-based monomers,
                      respectively. Our study represents a significant advancement
                      in the field of on-liquid surface chemistry and opens up
                      enormous opportunities for constructing C—C bond linked
                      2DP crystals with unique functionalities.},
      cin          = {FS DOOR-User},
      ddc          = {500},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20230315
                      (I-20230315) / FS-Proposal: I-20230364 (I-20230364) /
                      FC2DMOF - Development of Functional Conjugated
                      Two-Dimensional Metal-Organic Frameworks (852909) / T2DCP -
                      Development of Thiophene Based Conjugated Polymers in Two
                      Dimensions (819698) / DFG project G:(GEPRIS)426572620 -
                      Synthese von kristallinen, supramolekularen
                      Polyanilinschichten/2D-Polyanilinen und deren
                      Strukturbestimmung mittels Elektronenbeugung und
                      TEM-Bildgebung (426572620) / GRK 2861 - GRK 2861: Planare
                      Kohlenstoffgitter (491865171) / DFG project
                      G:(GEPRIS)417590517 - SFB 1415: Chemie der synthetischen
                      zweidimensionalen Materialien (417590517)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20230315 /
                      G:(DE-H253)I-20230364 / G:(EU-Grant)852909 /
                      G:(EU-Grant)819698 / G:(GEPRIS)426572620 /
                      G:(GEPRIS)491865171 / G:(GEPRIS)417590517},
      experiment   = {EXP:(DE-H253)P-P08-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:40921732},
      doi          = {10.1038/s41467-025-63768-6},
      url          = {https://bib-pubdb1.desy.de/record/637980},
}