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@ARTICLE{Betker:637648,
      author       = {Betker, Marie and Sochor, Benedikt and Erbes, Elisabeth and
                      Kurmanbay, Alisher and Erichlandwehr, Tim and Li, Yanan and
                      Müller-Buschbaum, Peter and Fernandez-Cuesta, Irene and
                      Techert, Simone A. and Söderberg, L. Daniel and Roth,
                      Stephan V.},
      title        = {{S}pray {D}eposition for {S}olvent {A}nnealing of {H}ybrid
                      {P}oly(3,4‐{E}thylenedioxythiophene) {P}olystyrene
                      {S}ulfonate {C}ellulose {S}ilver {N}anowire {C}omposite
                      {E}lectrodes {U}sing a {R}oll‐to‐{R}oll {C}oater},
      journal      = {Advanced engineering materials},
      volume       = {27},
      number       = {12},
      issn         = {1438-1656},
      address      = {Weinheim},
      publisher    = {Wiley-VCH Verl.},
      reportid     = {PUBDB-2025-03874},
      pages        = {2402354},
      year         = {2025},
      note         = {M.B. and S.V.R. thank DSF under grant DSF-33
                      “Investigation of processes for fabricating functional
                      multicomponent stacks based on nanopaper and
                      spray-coating” for funding. Y.L. and P.M.B. acknowledge
                      funding from the Deutsche Forschungsgemeinschaft (DFG,
                      German Research Foundation) via the International Research
                      Training Group 2022 Alberta/Technical University of Munich
                      International Graduate School for Environmentally
                      Responsible Functional Hybrid Materials (ATUMS).},
      abstract     = {Spray deposition is a rapid and facile technique for
                      coating surfaces on a large scale. The quality of these
                      coatings can be improved via post-treatment. One example is
                      solvent annealing, a well-known strategy to enhance the
                      conductivity of polymeric electrode materials using organic
                      solvents. Herein, the annealing of sprayed
                      poly(3,4-ethylenedioxythiophene) polystyrene sulfonate
                      (PEDOT:PSS)-based electrodes via solvent spray deposition in
                      a single roll-to-roll setup is reported. The annealing rates
                      of three solvents, namely dimethyl sulfoxide (DMSO),
                      isopropanol (IPA), and methanol (MeOH), depending on the
                      spray time and sprayed volume, are evaluated and correlated
                      with structural changes. The results show that the applied
                      method reduces the sheet resistance (R$_s$) of pure
                      PEDOT:PSS films by 82\% using DMSO and of cellulose-based
                      silver nanowire-PEDOT:PSS electrodes by 50\% using MeOH.
                      This approach allows for the facile and effective
                      combination of fabrication and quality enhancement of
                      sprayed, conductive polymer films using only one piece of
                      equipment. This approach makes the overall production
                      process of organic electrodes faster and cheaper and
                      therefore the usage of sustainable materials and fabrication
                      methods more attractive for the industry.},
      cin          = {DOOR ; HAS-User / FS DOOR-User / FS-PETRA-D / FS-SCS /
                      FS-SMA},
      ddc          = {660},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      $I:(DE-H253)FS_DOOR-User-20241023$ /
                      I:(DE-H253)FS-PETRA-D-20210408 / I:(DE-H253)FS-SCS-20131031
                      / I:(DE-H253)FS-SMA-20220811},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      SWEDEN-DESY - SWEDEN-DESY Collaboration
                      $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P03-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1002/adem.202402354},
      url          = {https://bib-pubdb1.desy.de/record/637648},
}