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@ARTICLE{Feng:637334,
author = {Feng, Shiyu and Sun, Baihong and Lu, Wenting and Zou,
Haikai and Wei, Chenxin and Zhang, Qian and Wang, Bihan and
Kunz, Martin and Kadobayashi, Hirokazu and Ahmad, Azkar
Saeed and Koren, Elad and Stavrou, Elissaios},
title = {{H}igh pressure structural and lattice dynamics study of
$α$-{I}n$_2${S}e$_3$},
journal = {The journal of chemical physics},
volume = {162},
number = {23},
issn = {0021-9606},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {PUBDB-2025-03826},
pages = {234505},
year = {2025},
abstract = {Layered $α$-In$_2$Se$_3$ has been studied using a combined
in situ synchrotron angle-dispersive powder x-ray
diffraction and Raman spectroscopy study in a diamond anvil
cell up to 60+ GPa, at room temperature. Helium, which
remains fairly hydrostatic up to the highest pressure in
this study, was used as the pressure-transmitting medium.
The results from both experimental methods reveal a
pressure-induced structural phase transition from
$α$-In$_2$Se$_3$ to a monoclinic $β′$-In$_2$Se$_3$
structure at ≈1 GPa, in agreement with previous studies.
Based on our detailed measurements using both experimental
techniques and the F–f formalism, the $β′$-In$_2$Se$_3$
structure remains stable up to 45 GPa, without a clear
indication of a phase transition toward the previously
reported $β$-In$_2$Se$_3$ phase. Above this pressure,
$_2$Se$_3$ adopts a disordered solid-solution-like
orthorhombic structure, phase IV. The results are discussed
in comparison with the relevant previous studies of
$α$-In$_2$Se$_3$ under pressure.},
cin = {FS DOOR-User / FS-PET-D},
ddc = {530},
cid = {$I:(DE-H253)FS_DOOR-User-20241023$ /
I:(DE-H253)FS-PET-D-20190712},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) /
FS-Proposal: I-20240513 (I-20240513)},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20240513},
experiment = {EXP:(DE-H253)P-P02.2-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1063/5.0266372},
url = {https://bib-pubdb1.desy.de/record/637334},
}