Home > Publications database > High‐Pressure Synthesis of Crystalline Double‐Layer Carbon Nitride Networks Stabilized in Bi$_7$C$_{ 10}$N$_{18}$(N$_{3(1‐ x )}$O$_{3x}$ ) > print

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024 7 _ |a 10.1002/anie.202506406
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100 1 _ |a Brüning, Lukas
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245 _ _ |a High‐Pressure Synthesis of Crystalline Double‐Layer Carbon Nitride Networks Stabilized in Bi$_7$C$_{ 10}$N$_{18}$(N$_{3(1‐ x )}$O$_{3x}$ )
260 _ _ |a Weinheim
|c 2025
|b Wiley-VCH
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500 _ _ |a CommunicationFigure 4. Phonon dispersion for a) Bi 7 C 10 N20 O and b) Bi 7 C 10 N18 O 3 at a synthesis pressure of 34 GPa. All calculated vibrational frequencies are real,indicating lattice dynamical stability. Projected electronic density of states (PDOS) for c) Bi 7 C 10 N20 O and d) Bi 7 C 10 N18 O 3 at 34 GPa.AcknowledgementsM.B. acknowledges the support of Deutsche Forschungsge-meinschaft (DFG Emmy-Noether project BY112/2-1).
520 _ _ |a Application of high-pressure conditions in chemical synthesis has proven to access a wide range of novel nitrogen-rich compounds and to overcome the stability of the dinitrogen molecule. In the present work, we report the high-pressurehigh-temperature (HPHT) synthesis of Bi$_7$C$_{ 10}$N$_{18}$(N$_{3(1‐ x )}$O$_{3x}$ ), which features double-layers of poly-N-(1,3,5-triazin-2-yl)-guanidine [C4 N6x- ]n and non-polymerized guanidinate anions CN 35- . The structure model was determined by means ofsynchrotron single-crystal X-ray diffraction and is fully corroborated by theoretical calculations. The poly-N-(1,3,5-triazin-2-yl)-guanidine illustrates an example of a 2D polymerized anionic C─N network and represents the first intermediatebetween highly charged CN 35− anions and fully condensed graphitic carbon nitride networks achieved by HPHT conditions.This opens a pathway to a widely varied family of hydrogen-free nitridocarbonates, which has the potential to develop intoan alternative synthesis route to classical polycondensation reactions
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700 1 _ |a Jena, Nityasagar
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700 1 _ |a Jurzick, Pascal L.
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700 1 _ |a Bykova, Elena
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700 1 _ |a Giordano, Nico
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700 1 _ |a Mezouar, Mohamed
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773 _ _ |a 10.1002/anie.202506406
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