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@ARTICLE{Cool:637157,
      author       = {Cool, Vincent and Steurs, Gert and Arcon, Iztok and Riano,
                      Sofia and Van Gerven, Tom and Binnemans, Koen},
      title        = {{S}peciation of {C}hlorido {C}omplexes of {R}hodium({III})
                      in {E}thylene {G}lycol},
      journal      = {Inorganic chemistry},
      volume       = {64},
      number       = {34},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {PUBDB-2025-03790},
      pages        = {17344 – 17358},
      year         = {2025},
      abstract     = {The speciation of rhodium(III) chlorido complexeswas
                      investigated in ethylene glycol, in the presence and absence
                      oflithium chloride, by rhodium-103 NMR and EXAFS
                      spectroscopy.All major rhodium(III) complexes were
                      identified based on theirspecies-specific isotopologue and
                      isotopomer patterns. EXAFSanalysis confirmed the results
                      deduced from the rhodium-103NMR spectra. The strikingly
                      different shifting behavior observedwith increasing lithium
                      chloride concentration was linked to theestablished behavior
                      of rhodium(III) in NMR spectroscopy.Density functional
                      theory (DFT) calculations were performed toelucidate the
                      underlying factors of the observed trends, highlightingtheir
                      potential as an additional tool for the speciation
                      ofrhodium(III) complexes, even for NMR spectra with a
                      lowsignal-to-noise ratio. These results give a deeper
                      insight into the speciation of rhodium(III) in a nonaqueous
                      environment andcontribute to the fundamental basis needed to
                      understand the extraction behavior of rhodium(III) in
                      nonaqueous solvent extraction.},
      cin          = {FS DOOR-User},
      ddc          = {540},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20230851
                      EC (I-20230851-EC)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20230851-EC},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1021/acs.inorgchem.5c02591},
      url          = {https://bib-pubdb1.desy.de/record/637157},
}