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| Home > Publications database > Revealing the Hidden Polysulfides in Solid-State Na–S Batteries: How Pressure and Electrical Transport Control Kinetic Pathways > print |
| 001 | 636702 | ||
| 005 | 20250907054621.0 | ||
| 024 | 7 | _ | |a 10.1021/jacs.5c00465 |2 doi |
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| 100 | 1 | _ | |a Nguyen, Hung Quoc |0 P:(DE-H253)PIP1104792 |b 0 |
| 245 | _ | _ | |a Revealing the Hidden Polysulfides in Solid-State Na–S Batteries: How Pressure and Electrical Transport Control Kinetic Pathways |
| 260 | _ | _ | |a Washington, DC |c 2025 |b ACS Publications |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Room temperature operation of Na−S batterieswith liquid electrolytes is plagued by fundamental challengesstemming from polysulfide solubility and their shuttle effects.Inorganic solid electrolytes offer a promising solution by acting asbarriers to polysulfide migration, mitigating capacity loss. While thesequential formation of cycling products in molten-electrode andliquid electrolytes-based Na−S batteries generally aligns with theexpectations from the Na−S phase diagram, their presence,stability, and transitory behavior in systems with inorganic solidelectrolytes at room temperature, remain poorly understood. Toaddress this, we employed operando scanning microbeam X-raydiffraction, operando X-ray photoelectron spectroscopy and ex-situX-ray absorption spectroscopy to investigate the sulfur conversionmechanisms in Na−S cells with Na3PS4 and Na4(B10H10)(B12H12) electrolytes. Our findings reveal the formation of crystalline andamorphous polysulfides, including those predicted by the Na−S phase diagram (e.g., Na2S5, Na2S4, Na2S2, Na2S), high-orderpolysulfides observed in liquid-electrolyte systems (e.g., Na2Sx, where x = 6−8), and phases like Na2S3 typically stable only underhigh-temperature or high-pressure conditions. We demonstrate that these transitions are governed by diffusion-limited kinetics andlocalized stress concentrations, emphasizing the critical role of pressure, which serves as both a thermodynamic variable, as well as adesign parameter, for optimizing solid-state Na−S battery performance necessary for pushing these cells closer to the commercialfrontier. |
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| 700 | 1 | _ | |a Rettenwander, Daniel |0 P:(DE-H253)PIP1112081 |b 16 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/jacs.5c00465 |g Vol. 147, no. 27, p. 23492 - 23503 |0 PERI:(DE-600)1472210-0 |n 27 |p 23492 - 23503 |t Journal of the American Chemical Society |v 147 |y 2025 |x 0002-7863 |
| 856 | 4 | _ | |y OpenAccess |u https://bib-pubdb1.desy.de/record/636702/files/Nguyen_JACS_2025.pdf |
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