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@ARTICLE{Bloss:633849,
      author       = {Bloss, Dana and Dupuy, Remi and Trinter, Florian and Unger,
                      Isaak and Walsh, Noelle and Oehrwall, Gunnar and Golchert,
                      Niklas and Klassen, Gabriel and Krone, Adrian Peter and
                      Terao, Yusaku and Viehmann, Johannes and Wülfing, Lasse and
                      Richter, Clemens and Buttersack, Tillmann and Cederbaum,
                      Lorenz and Hergenhahn, Uwe and Bjoerneholm, Olle and
                      Ehresmann, Arno and Hans, Andreas},
      title        = {{S}ite- and {E}nergy-{S}elective {L}ow-{E}nergy {E}lectron
                      {E}mission by {X}-rays in the {A}queous {P}hase},
      journal      = {Journal of the American Chemical Society},
      volume       = {147},
      number       = {25},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {PUBDB-2025-02450},
      pages        = {22115 - 22120},
      year         = {2025},
      note         = {Open Access},
      abstract     = {Low-energy-electron emission from resonant Auger final
                      states via intermolecular Coulombic decay (RA-ICD) has
                      previously been described as a promising scenario for
                      controlling radiation damage for medical purposes, but it
                      has so far only been observed in prototypical atomic and
                      molecular van der Waals dimers and clusters. Here, we report
                      the experimental observation of RA-ICD in an aqueous
                      solution. We show that for solvated Ca2+ ions, the emission
                      can be very efficiently controlled by tuning the photon
                      energy of exciting X-rays to inner-shell resonances of the
                      ions. Our results provide the next step from demonstrating
                      RA-ICD in relatively simple prototype systems to
                      understanding the relevance and potential applications of
                      ICD in real-life scenarios.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20211422
                      (I-20211422) / 05K22RK2 - Verbundprojekt 05K2022 -
                      GPHASE-CC: Fertigstellung und Inbetriebnahme der Endstation
                      zur Gasphasen-Spektroskopie bei BESSY. Teilprojekt 2: VMI
                      und Realisierung koinzidenter Elektron-Photon Messungen.
                      (BMBF-05K22RK2) / 05K22RK1 - Verbundprojekt 05K2022 -
                      TRANSALP: Zeit- $\&$ winkelaufgelöste Spektroskopie an
                      Proben in der flüssigen Phase. Teilprojekt 2: Aufbau Liquid
                      Jet und KI-basierte Datenanalyse. (BMBF-05K22RK1) / SFB 1319
                      C06 - Photoneninduzierte chirale Wechselwirkungen zur
                      Detektion und Trennung von Enantiomeren (C06*) (491565418) /
                      DFG project G:(GEPRIS)509471550 - Dynamik
                      photoionisations-induzierter Prozesse in laser-präparierten
                      Molekülen in der Gasphase und der wässrigen Phase
                      (509471550) / $ETMD_ICEC$ - Efficient pathways to
                      neutralization and radical production enabled by environment
                      (692657) / AQUACHIRAL - Chiral aqueous-phase chemistry
                      (883759) / SWEDEN-DESY - SWEDEN-DESY Collaboration
                      $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20211422 /
                      G:(DE-Ds200)BMBF-05K22RK2 / G:(DE-Ds200)BMBF-05K22RK1 /
                      G:(GEPRIS)491565418 / G:(GEPRIS)509471550 /
                      G:(EU-Grant)692657 / G:(EU-Grant)883759 /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P04-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:40513115},
      doi          = {10.1021/jacs.5c06436},
      url          = {https://bib-pubdb1.desy.de/record/633849},
}