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000633795 1001_ $$0P:(DE-H253)PIP1101133$$aLiu, Shilei$$b0
000633795 245__ $$aRevealing solidification behaviour and phase transformations in Fe$_{60}$Co$_{25}$Ni$_{10}$Mo$_5$ and Fe$_{63}$Co$_{26}$Ni$_{11}$ alloys by using high-speed video and in situ X-ray diffraction
000633795 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2025
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000633795 520__ $$aA combination of time-resolved synchrotron X-ray diffraction (XRD), high-speed video and electromagnetic levitation (EML) enabled revealing the solidification path and phase transformations in Fe$_{60}$Co$_{25}$Ni$_{10}$Mo$_5$ and Fe$_{63}$Co$_{26}$Ni$_{11}$ alloys during heating and cooling. High-speed XRD provided direct evidence for nucleation of metastable δ-ferrite in undercooled liquid state and its quick transformation to γ-austenite. Addition of Mo clearly favours nucleation of $δ$-ferrite in Fe$_{60}$Co$_{25}$Ni$_{10}$Mo$_5$ melts undercooled by $Δ$T of about 100 K and more. In contrast, primary crystallisation of any of $δ$ and γ phases appears to be possible in Fe$_{63}$Co$_{26}$Ni$_{11}$ melts at all levels of undercooling. Neither Ni nor Mo exhibit any notable effect on the growth behaviour of $δ$ and $γ$ phases, which remains close to the one in the Fe$_{60}$Co$_{40}$ base alloy. Alloying with Mo has a strong impact on the microstructure and solid state transformations in the Fe$_{60}$Co$_{25}$Ni$_{10}$Mo$_5$ samples such as grain refinement at $Δ$T < 200 K, incomplete transformation of $γ$-austenite to $α$-ferrite, and formation of martensite at $Δ$T ≥ 330 K.
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000633795 7001_ $$0P:(DE-H253)PIP1091141$$aKaban, Victoria$$b1
000633795 7001_ $$0P:(DE-H253)PIP1007064$$aGutowski, Olof$$b2$$udesy
000633795 7001_ $$00000-0003-4318-2441$$aVolkmann, Thomas$$b3
000633795 7001_ $$0P:(DE-HGF)0$$aNielsch, Kornelius$$b4
000633795 7001_ $$0P:(DE-H253)PIP1007906$$aKaban, Ivan$$b5$$eCorresponding author
000633795 773__ $$0PERI:(DE-600)2014621-8$$a10.1016/j.actamat.2025.121017$$gVol. 292, p. 121017 -$$p121017 $$tActa materialia$$v292$$x1359-6454$$y2025
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