guest ::
| Home > Publications database > Titanium Substitution to Advance the Prospect of NaMnO$_2$ Cathodes for Practical Application in Sodium-Ion Batteries > print |
| Home > Publications database > Titanium Substitution to Advance the Prospect of NaMnO$_2$ Cathodes for Practical Application in Sodium-Ion Batteries > print |
| 001 | 633262 | ||
| 005 | 20250831054618.0 | ||
| 024 | 7 | _ | |a 10.1021/acsaem.5c01367 |2 doi |
| 024 | 7 | _ | |a 10.3204/PUBDB-2025-02388 |2 datacite_doi |
| 024 | 7 | _ | |a altmetric:179384866 |2 altmetric |
| 037 | _ | _ | |a PUBDB-2025-02388 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a An, Siyu |0 P:(DE-H253)PIP1107283 |b 0 |
| 245 | _ | _ | |a Titanium Substitution to Advance the Prospect of NaMnO$_2$ Cathodes for Practical Application in Sodium-Ion Batteries |
| 260 | _ | _ | |a Washington, DC |c 2025 |b ACS Publications |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1756106364_2536571 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a O3-type layered oxides stand out among various Na-ion battery cathodes due to their unparalleled theoretical specific capacities. As a representative of low-cost, Mn-based cathode materials, $α$-NaMnO$_2$ (NMO) has attracted great attention. However, its practical application is hindered by poor reversibility. Compared to other O3 or O′3-type layered oxides, such as NaNiO2, NMO undergoes multiple phase transitions, with the final O1 phase negatively affecting cycling performance. In this study, precipitated Mn$_3$O$_4$ was employed, to our knowledge for the first time, as a precursor in the synthesis of NMO, and the cathode material was systematically optimized through incremental improvement via titanium substitution. NaMn$_{0.9}$Ti$_{0.1}$O$_2$ was found to exhibit enhanced stability, with the capacity retention increasing from 42 to 70% after 50 cycles at C/10, along with superior rate capability over NMO. This is due in part to titanium’s role in facilitating primary particle (grain) growth and suppressing O1 phase formation, thereby preserving structural integrity and mitigating degradation caused by volume variations and irreversible oxygen redox during battery operation. This work not only provides valuable insights into the development of next-generation NMO cathodes but also advances their potential for practical applications. |
| 536 | _ | _ | |a 6G3 - PETRA III (DESY) (POF4-6G3) |0 G:(DE-HGF)POF4-6G3 |c POF4-6G3 |f POF IV |x 0 |
| 536 | _ | _ | |a FS-Proposal: I-20230867 (I-20230867) |0 G:(DE-H253)I-20230867 |c I-20230867 |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
| 693 | _ | _ | |a PETRA III |f PETRA Beamline P02.1 |1 EXP:(DE-H253)PETRAIII-20150101 |0 EXP:(DE-H253)P-P02.1-20150101 |6 EXP:(DE-H253)P-P02.1-20150101 |x 0 |
| 700 | 1 | _ | |a Sahu, Rajib |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Zhang, Ruizhuo |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Ulusoy, Fatih |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Kübel, Christian |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Kondrakov, Aleksandr |0 P:(DE-H253)PIP1025977 |b 5 |e Corresponding author |
| 700 | 1 | _ | |a Janek, Juergen |0 P:(DE-H253)PIP1023994 |b 6 |
| 700 | 1 | _ | |a Brezesinski, Torsten |0 P:(DE-H253)PIP1007361 |b 7 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acsaem.5c01367 |g p. acsaem.5c01367 |0 PERI:(DE-600)2916551-9 |n 14 |p 10508 - 10518 |t ACS applied energy materials |v 8 |y 2025 |x 2574-0962 |
| 856 | 4 | _ | |y Published on 2025-07-11. Available in OpenAccess from 2026-07-11. |u https://bib-pubdb1.desy.de/record/633262/files/NMTO_MS_Revised.pdf |
| 856 | 4 | _ | |y Published on 2025-07-11. Available in OpenAccess from 2026-07-11. |x pdfa |u https://bib-pubdb1.desy.de/record/633262/files/NMTO_MS_Revised.pdf?subformat=pdfa |
| 909 | C | O | |o oai:bib-pubdb1.desy.de:633262 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 0 |6 P:(DE-H253)PIP1107283 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 1 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 2 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 3 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 4 |6 P:(DE-HGF)0 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 5 |6 P:(DE-H253)PIP1025977 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 6 |6 P:(DE-H253)PIP1023994 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 7 |6 P:(DE-H253)PIP1007361 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Großgeräte: Materie |1 G:(DE-HGF)POF4-6G0 |0 G:(DE-HGF)POF4-6G3 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v PETRA III (DESY) |x 0 |
| 914 | 1 | _ | |y 2025 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |d 2024-12-11 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b ACS APPL ENERG MATER : 2022 |d 2024-12-11 |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b ACS APPL ENERG MATER : 2022 |d 2024-12-11 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2024-12-11 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2024-12-11 |
| 920 | 1 | _ | |0 I:(DE-H253)HAS-User-20120731 |k DOOR ; HAS-User |l DOOR-User |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-H253)HAS-User-20120731 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|