000633158 001__ 633158
000633158 005__ 20250824054418.0
000633158 0247_ $$2doi$$a10.1021/acsnano.5c07289
000633158 0247_ $$2ISSN$$a1936-0851
000633158 0247_ $$2ISSN$$a1936-086X
000633158 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-02354
000633158 0247_ $$2altmetric$$aaltmetric:179284455
000633158 0247_ $$2pmid$$apmid:40634268
000633158 037__ $$aPUBDB-2025-02354
000633158 041__ $$aEnglish
000633158 082__ $$a540
000633158 1001_ $$aHiller, Jonas L.$$b0
000633158 245__ $$aMechanically Robust Supercrystals from Antisolvent-Induced Assembly of Perovskite Nanocrystals
000633158 260__ $$aWashington, DC$$bSoc.$$c2025
000633158 3367_ $$2DRIVER$$aarticle
000633158 3367_ $$2DataCite$$aOutput Types/Journal article
000633158 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1755599701_4431
000633158 3367_ $$2BibTeX$$aARTICLE
000633158 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000633158 3367_ $$00$$2EndNote$$aJournal Article
000633158 520__ $$aOrdered arrays of nanocrystals, called supercrystals, have attracted significant attention owing to the collective quantum effects arising from the coupling between neighboring nanocrystals. In particular, lead halide perovskite nanocrystals are widely used because of the combination of the optical properties and faceted cubic shape, which enables the formation of highly ordered supercrystals. The most frequently used method for the fabrication of perovskite supercrystals is based on the self-assembly of nanocrystals from solution via slow evaporation of the solvent. However, the supercrystals produced with this technique grow in random positions on the substrate. Moreover, they are mechanically soft due to the presence of organic ligands around the individual nanocrystals. Therefore, such supercrystals cannot be easily manipulated with microgrippers, which hinders their use in applications. In this work, we synthesize mechanically robust supercrystals built from cubic lead halide perovskite nanocrystals by a two-layer phase diffusion self-assembly with acetonitrile as the antisolvent. This method yields highly faceted thick supercrystals, which are robust enough to be picked up and relocated by microgrippers. We employed X-ray nanodiffraction together with high-resolution scanning electron microscopy and atomic force microscopy to reveal the structure of CsPbBr3, CsPbBr2Cl, and CsPbCl3 supercrystals assembled using the two-layer phase diffusion technique and explain their unusual mechanical robustness. Our findings are crucial for further experiments and applications in which supercrystals need to be placed in a precise location, for example, between the electrodes in an electro-optical modulator.
000633158 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x0
000633158 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x1
000633158 536__ $$0G:(DE-H253)I-20230782$$aFS-Proposal: I-20230782 (I-20230782)$$cI-20230782$$x2
000633158 536__ $$0G:(GEPRIS)546072194$$aDFG project G:(GEPRIS)546072194 - Erhöhung von struktureller Kohärenz und optischem Koppeln in Superkristallen aus Nanopartikeln (546072194)$$c546072194$$x3
000633158 536__ $$0G:(GEPRIS)426008387$$aDFG project G:(GEPRIS)426008387 - Optoelektronik Synthetischer Mesokristalle (426008387)$$c426008387$$x4
000633158 536__ $$0G:(EU-Grant)101039683$$aPROMETHEUS - Engineering of Superfluorescent Nanocrystal Solids (101039683)$$c101039683$$fERC-2021-STG$$x5
000633158 536__ $$0G:(DE-Ds200)BMBF-05K22MG1$$a05K22MG1 - Methodische Entwicklung eines neuen Phasenkontrast-Tomographie Verfahrens mit holographischer Bildrekonstruktion (Holo-Tomographie). (BMBF-05K22MG1)$$cBMBF-05K22MG1$$f05K22MG1$$x6
000633158 693__ $$0EXP:(DE-H253)P-P10-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P10-20150101$$aPETRA III$$fPETRA Beamline P10$$x0
000633158 7001_ $$0P:(DE-H253)PIP1106362$$aThalwitzer, Robert$$b1
000633158 7001_ $$0P:(DE-HGF)0$$aBozkurt, Ata$$b2
000633158 7001_ $$00000-0002-1446-1671$$aFerreira, Matheus Gomes$$b3
000633158 7001_ $$0P:(DE-HGF)0$$aHodak, Richard$$b4
000633158 7001_ $$0P:(DE-HGF)0$$aStrauß, Fabian$$b5
000633158 7001_ $$0P:(DE-HGF)0$$aNadler, Elke$$b6
000633158 7001_ $$0P:(DE-H253)PIP1102078$$aHinsley, Gerard$$b7
000633158 7001_ $$0P:(DE-H253)PIP1081817$$aWang, Bihan$$b8
000633158 7001_ $$0P:(DE-H253)PIP1102996$$aNgoi, Kuan Hoon$$b9
000633158 7001_ $$0P:(DE-H253)PIP1111431$$aRudzinski, Witold$$b10
000633158 7001_ $$0P:(DE-H253)PIP1088034$$aKneschaurek, Ekaterina$$b11
000633158 7001_ $$0P:(DE-H253)PIP1004234$$aRoseker, Wojciech$$b12
000633158 7001_ $$0P:(DE-H253)PIP1007141$$aSprung, Michael$$b13
000633158 7001_ $$0P:(DE-H253)PIP1081202$$aLapkin, Dmitrii$$b14
000633158 7001_ $$0P:(DE-H253)PIP1112071$$aBaranov, Dmitry$$b15
000633158 7001_ $$0P:(DE-H253)PIP1008437$$aSchreiber, Frank$$b16
000633158 7001_ $$0P:(DE-H253)PIP1003481$$aVartanyants, Ivan A.$$b17
000633158 7001_ $$0P:(DE-H253)PIP1023788$$aScheele, Marcus$$b18$$eCorresponding author
000633158 7001_ $$0P:(DE-H253)PIP1014884$$aZaluzhnyy, Ivan A.$$b19$$eCorresponding author
000633158 773__ $$0PERI:(DE-600)2383064-5$$a10.1021/acsnano.5c07289$$n28$$p26117$$tACS nano$$v19$$x1936-0851$$y2025
000633158 8564_ $$uhttps://pubs.acs.org/doi/10.1021/acsnano.5c07289
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/HTML-Approval_of_scientific_publication.html
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/Internal%20Review%20.pdf
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/PDF-Approval_of_scientific_publication.pdf
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/Internal%20Review%20.pdf?subformat=pdfa$$xpdfa
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/hiller-et-al-2025-mechanically-robust-supercrystals-from-antisolvent-induced-assembly-of-perovskite-nanocrystals.pdf$$yOpenAccess
000633158 8564_ $$uhttps://bib-pubdb1.desy.de/record/633158/files/hiller-et-al-2025-mechanically-robust-supercrystals-from-antisolvent-induced-assembly-of-perovskite-nanocrystals.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000633158 909CO $$ooai:bib-pubdb1.desy.de:633158$$pdnbdelivery$$pec_fundedresources$$pVDB$$pdriver$$popen_access$$popenaire
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1106362$$aExternal Institute$$b1$$kExtern
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1102078$$aDeutsches Elektronen-Synchrotron$$b7$$kDESY
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1102078$$aExternal Institute$$b7$$kExtern
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1081817$$aDeutsches Elektronen-Synchrotron$$b8$$kDESY
000633158 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1081817$$aEuropean XFEL$$b8$$kXFEL.EU
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1102996$$aExternal Institute$$b9$$kExtern
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1111431$$aDeutsches Elektronen-Synchrotron$$b10$$kDESY
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1111431$$aExternal Institute$$b10$$kExtern
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1088034$$aExternal Institute$$b11$$kExtern
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1004234$$aDeutsches Elektronen-Synchrotron$$b12$$kDESY
000633158 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1004234$$aEuropean XFEL$$b12$$kXFEL.EU
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1007141$$aDeutsches Elektronen-Synchrotron$$b13$$kDESY
000633158 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1007141$$aEuropean XFEL$$b13$$kXFEL.EU
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1081202$$aDeutsches Elektronen-Synchrotron$$b14$$kDESY
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1081202$$aExternal Institute$$b14$$kExtern
000633158 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1081202$$aEuropean XFEL$$b14$$kXFEL.EU
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1112071$$aExternal Institute$$b15$$kExtern
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1008437$$aExternal Institute$$b16$$kExtern
000633158 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1003481$$aDeutsches Elektronen-Synchrotron$$b17$$kDESY
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1003481$$aExternal Institute$$b17$$kExtern
000633158 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1003481$$aEuropean XFEL$$b17$$kXFEL.EU
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1023788$$aExternal Institute$$b18$$kExtern
000633158 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1014884$$aExternal Institute$$b19$$kExtern
000633158 9131_ $$0G:(DE-HGF)POF4-632$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vMaterials – Quantum, Complex and Functional Materials$$x0
000633158 9131_ $$0G:(DE-HGF)POF4-6G3$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vPETRA III (DESY)$$x1
000633158 9141_ $$y2025
000633158 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2025-01-07
000633158 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000633158 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bACS NANO : 2022$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000633158 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bACS NANO : 2022$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2025-01-07
000633158 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2025-01-07
000633158 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x0
000633158 9201_ $$0I:(DE-H253)FS-PETRA-S-20210408$$kFS-PETRA-S$$lPETRA-S$$x1
000633158 9201_ $$0I:(DE-H253)FS-PS-20131107$$kFS-PS$$lFS-Photon Science$$x2
000633158 980__ $$ajournal
000633158 980__ $$aVDB
000633158 980__ $$aUNRESTRICTED
000633158 980__ $$aI:(DE-H253)HAS-User-20120731
000633158 980__ $$aI:(DE-H253)FS-PETRA-S-20210408
000633158 980__ $$aI:(DE-H253)FS-PS-20131107
000633158 9801_ $$aFullTexts