% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Kraus:633155,
author = {Kraus, Irene and Wu, Mingjian and Rechberger, Stefanie and
Will, Johannes and Maiti, Santanu and Kuhlmann, Andreas and
Huck, Marten and Lüer, Larry and Bertram, Florian and
Steinrueck, Hans-Georg and Unruh, Tobias and Brabec,
Christoph J. and Spiecker, Erdmann},
title = {3{D} {E}lectron {D}iffraction as {GIWAXS} {A}lternative for
{Q}uantitative {S}tructural {C}haracterization of {O}rganic
{S}olar {C}ells},
reportid = {PUBDB-2025-02351, arXiv:2502.11254},
year = {2025},
note = {23AcknowledgementsThe authors gratefully acknowledge
funding by the German Research Foundation (DFG) through
theCollaborative Research Center SFB 953 “Synthetic carbon
allotropes” and the Research Training GroupGRK 1896 “In
situ microscopy with electrons, x-rays and scanning
probes.”},
abstract = {We demonstrate elastically filtered 3D Electron Diffraction
(3D ED) as a powerful alternative technique to Grazing
Incidence Wide-Angle X-ray Scattering (GIWAXS) for
quantitatively characterizing the structure of organic
semiconductor films. Using a model material system of
solvent vapor annealed DRCN5T:PC71BM thin film, which is
employed in organic solar cells (OSCs), we extract the
structural data obtained from 3D ED and compare with that
from GIWAXS, utilizing both laboratory and synchrotron X-ray
sources. Quantitative evaluation of the datasets in terms of
peak positions, peak widths and mosaicity revealed good
agreement between both techniques, qualifying 3D ED as an
alternative tool for analyzing highly beam-sensitive organic
thin films. Furthermore, the respective advantages and
limitations of 3D ED and GIWAXS are discussed, emphasizing
the unique capability of 3D ED to integrate seamlessly with
the diverse imaging and spectroscopic modalities in modern
TEM. This integration enriches the techniques of structural
characterization of OSCs, paving the way for deeper insights
into their structural properties and ultimately their
performance.},
keywords = {Materials Science (cond-mat.mtrl-sci) (Other) / FOS:
Physical sciences (Other)},
cin = {DOOR ; HAS-User / FS-PET-D},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PET-D-20190712},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
FS-Proposal: R-20240703 (R-20240703) / DFG project
G:(GEPRIS)182849149 - SFB 953: Synthetische
Kohlenstoffallotrope (182849149) / GRK 1896 - GRK 1896:
In-situ-Mikroskopie mit Elektronen, Röntgenstrahlen und
Rastersonden (218975129)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)R-20240703 / G:(GEPRIS)182849149 /
G:(GEPRIS)218975129},
experiment = {EXP:(DE-H253)P-P08-20150101},
typ = {PUB:(DE-HGF)25},
eprint = {2502.11254},
howpublished = {arXiv:2502.11254},
archivePrefix = {arXiv},
SLACcitation = {$\%\%CITATION$ = $arXiv:2502.11254;\%\%$},
doi = {10.3204/PUBDB-2025-02351},
url = {https://bib-pubdb1.desy.de/record/633155},
}