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@ARTICLE{Zhou:633011,
author = {Zhou, Weijun and Strmšek, Žiga and Snoj, Jaka and
Škarabot, Miha and Jerala, Roman},
title = {{P}rogrammable {P}rotein‐{DNA} {C}omposite
{N}anostructures: from {N}anostructure {C}onstruction to
{P}rotein‐{I}nduced {M}icro‐{S}cale {M}aterial
{S}elf‐{A}ssembly and {F}unctionalization},
journal = {Small},
volume = {21},
number = {30},
issn = {1613-6810},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {PUBDB-2025-02337},
pages = {2502060},
year = {2025},
abstract = {The integration of DNA and protein-designed nanostructures
represents a transformative approach to the development of
programmable biopolymers for nanoscale construction. While
DNA nanostructures excel in the readily programmable
precision and scalability of base pairing, protein
assemblies exploit the chemical diversity of amino acids for
greater functional versatility. Here a platform is presented
that unifies these two paradigms by combining coiled-coil
protein origami with DNA nanostructures through orthogonal
protein-protein (SpyCatcher-SpyTag) and protein-DNA
(DCV-DNA) covalent conjugation strategies. This
dual-functionalization strategy enables the construction of
stable and versatile protein-DNA composites capable of
hierarchical self-assembly. This shows that these composites
drive the transformation of DNA nanotubes into large-scale,
patterned nanofibers or nanorods, with the proteins
regularly distributed over their surface and retaining their
enzymatic and fluorescent functions. In addition, a
DNA-luciferase circuit is developed through split enzyme
reconstitution to achieve reversible regulation of enzymatic
activity, highlighting the dynamic functionality of these
composites. This introduces a modular approach to producing
multifunctional bio-nanomaterials, highlighting the
potential of protein-DNA composite nanostructures as a
bridge between molecular design and functional nanomaterials
and paves the way for the development of dynamic bio-devices
and programmable biomaterials.},
cin = {EMBL-User},
ddc = {620},
cid = {I:(DE-H253)EMBL-User-20120814},
pnm = {6G3 - PETRA III (DESY) (POF4-6G3) / LoopOfFun - Closed-loop
control of fungal materials (101070817)},
pid = {G:(DE-HGF)POF4-6G3 / G:(EU-Grant)101070817},
experiment = {EXP:(DE-H253)P-P12-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:40442952},
doi = {10.1002/smll.202502060},
url = {https://bib-pubdb1.desy.de/record/633011},
}