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@ARTICLE{RosaDomingos:631524,
author = {Rosa Domingos, Sérgio Miguel and Martin, Kévin and
Avarvari, Narcis and Schnell, Melanie},
title = {{W}ater {D}ocking {B}ias in [4]{H}elicene},
journal = {Angewandte Chemie},
volume = {131},
number = {33},
issn = {0932-2132},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {PUBDB-2025-02036},
pages = {11379 - 11383},
year = {2019},
note = {Waiting for fulltext},
abstract = {We report on the one- and two-water clusters of
[4]helicene, the smallest polycyclic aromatic hydrocarbon
with a helical sense, which were captured in the gas phase
using high-resolution rotational spectroscopy. The
structures of the complexes are unambiguously revealed using
microwave spectra of isotopically enriched species. In the
one-water cluster, the apparent splitting pattern is
consistent with a tunneling motion that encompasses an
exchange of strongly and weakly bonded water hydrogens. This
motion is “locked” in the two-water cluster. The
relevant intermolecular contacts, symmetry, and aromaticity
effects are unveiled for the microsolvated chiral
topologies. These observations entail the first glance at
the structures and internal dynamics of the water binding
motifs of a chiral polycyclic aromatic hydrocarbon.},
cin = {FS-SMP},
ddc = {660},
cid = {I:(DE-H253)FS-SMP-20171124},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / DFG project G:(GEPRIS)328961117 - SFB 1319:
Extremes Licht zur Analyse und Kontrolle molekularer
Chiralität (ELCH) (328961117)},
pid = {G:(DE-HGF)POF4-631 / G:(GEPRIS)328961117},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
doi = {10.1002/ange.201902889},
url = {https://bib-pubdb1.desy.de/record/631524},
}