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@ARTICLE{Yin:631478,
      author       = {Yin, Zhaohui and Gao, Zirui and Luo, Lan and Zhang, Xiaohui
                      and Hou, Wenxiang and Dai, Wenjing and Tian, Shuheng and
                      Qin, Xuetao and Wang, Maolin and Peng, Mi and Li, Kaihua and
                      Wang, Songbo and Zhang, Lei and Wang, Hong and Li, Jianxin
                      and Zhu, Qingjun and Cheng, Bowen and Yin, Zhen and Ma,
                      Ding},
      title        = {{A} {G}reen and {E}fficient {E}lectrocatalytic {R}oute for
                      the {H}ighly‐{S}elective {O}xidation of {C}−{H} {B}onds
                      in {A}romatics over 1{D} {C}o$_3${O}$_4$ ‐{B}ased
                      {N}anoarrays},
      journal      = {Angewandte Chemie},
      volume       = {137},
      number       = {3},
      issn         = {0932-2132},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2025-01990},
      pages        = {e202415044},
      year         = {2025},
      note         = {Waiting for fulltext},
      abstract     = {Electrocatalytic oxidation of C−H bonds in hydrocarbons
                      represents an efficient and sustainable strategy for the
                      synthesis of value-added chemicals. Herein, a highly
                      selective and continuous-flow electrochemical oxidation
                      process of toluene to various oxygenated products (benzyl
                      alcohol, benzaldehyde, and benzyl acetate) is developed with
                      the electrocatalytic membrane electrodes (ECMEs). The
                      selectivity of target products can be manipulated via
                      surface and interface engineering of Co$_3$O$_4$-based
                      electrocatalysts. We achieved a high benzaldehyde
                      selectivity of 90 \% at a toluene conversion of 47.6 \%
                      using 1D Co$_3$O$_4$ nanoneedles (NNs) loaded on a
                      microfiltration (MF) titanium (Ti) membrane, i.e,
                      Co$_3$O$_4$ NNs/Ti. In contrast, the main product shifted to
                      benzyl alcohol with a selectivity of 90.1 \% at a
                      conversion of 32.1 \% after modifying MnO2 nanosheets
                      (NSs) on Co3O4 NNs/Ti (Co$_3$O$_4$@MnO$_2$/Ti) catalyst.
                      Moreover, benzyl acetate product can be obtained with a
                      selectivity of 92 \% at a conversion of 58.5 \% at high
                      current density (>1.5 mA cm−2), demonstrating that the
                      pathway of toluene oxidation is readily maneuvered. DFT
                      results reveal that modifying MnO$_2$ on Co$_3$O$_4$
                      optimizes the electron structure of Co$_3$O$_4$@MnO$_2$/Ti
                      and modulates the adsorption behavior of intermediate
                      species. This work demonstrates a sustainable, efficient,
                      and continuous-flow process for precise control over the
                      production selectivity of value-added oxygenated derivatives
                      in the electrochemical oxidation of aromatic hydrocarbons.},
      cin          = {$Z_PITZ$},
      ddc          = {660},
      cid          = {$I:(DE-H253)Z_PITZ-20210408$},
      pnm          = {621 - Accelerator Research and Development (POF4-621)},
      pid          = {G:(DE-HGF)POF4-621},
      experiment   = {EXP:(DE-MLZ)NOSPEC-20140101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1002/ange.202415044},
      url          = {https://bib-pubdb1.desy.de/record/631478},
}