000631049 001__ 631049
000631049 005__ 20250715151532.0
000631049 0247_ $$2doi$$a10.1103/PhysRevLett.134.236203
000631049 0247_ $$2ISSN$$a0031-9007
000631049 0247_ $$2ISSN$$a1092-0145
000631049 0247_ $$2ISSN$$a1079-7114
000631049 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-01918
000631049 0247_ $$2openalex$$aopenalex:W4411277892
000631049 037__ $$aPUBDB-2025-01918
000631049 041__ $$aEnglish
000631049 082__ $$a530
000631049 1001_ $$0P:(DE-H253)PIP1030341$$aTober, Steffen$$b0$$eCorresponding author$$udesy
000631049 245__ $$aSite-Resolved Near-Surface Cation Diffusion in Magnetite
000631049 260__ $$aCollege Park, Md.$$bAPS$$c2025
000631049 3367_ $$2DRIVER$$aarticle
000631049 3367_ $$2DataCite$$aOutput Types/Journal article
000631049 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1750334446_1699581
000631049 3367_ $$2BibTeX$$aARTICLE
000631049 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000631049 3367_ $$00$$2EndNote$$aJournal Article
000631049 520__ $$aIn situ nuclear forward scattering shows a thermally induced cation exchange between a 57 Fe3 ⁢O4 thin-film and a Fe3⁢ O4 (001) substrate predominantly in the octahedral sublattice for a temperature range between 470 and 710 K. The overall activation barrier in this temperature range is found to be 19±32  kJ/mol, which is significantly lower than expected from extrapolating a bulk diffusion model. This observation can be attributed to the large out-of-equilibrium cation deficit as determined by surface x-ray diffraction. Despite the relatively low hopping barrier, the diffusion constant is about 5 orders of magnitude lower than expected for magnetite having an equilibrium cation stoichiometry. The results are relevant for applications relying on the near-surface structure and stoichiometry of magnetite, and we argue that the correlation between cation diffusion and stoichiometry may play a role for a wider range of oxide materials.
000631049 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x0
000631049 536__ $$0G:(GEPRIS)318029273$$aSFB 986 C07 - Deposition und Stabilität von hochtemperaturfesten geschichteten Metamaterialien (C07) (318029273)$$c318029273$$x1
000631049 536__ $$0G:(GEPRIS)192346071$$aDFG project G:(GEPRIS)192346071 - SFB 986: Maßgeschneiderte Multiskalige Materialsysteme - M3 (192346071)$$c192346071$$x2
000631049 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000631049 693__ $$0EXP:(DE-H253)Nanolab-01-20150101$$1EXP:(DE-H253)DESY-NanoLab-20150101$$5EXP:(DE-H253)Nanolab-01-20150101$$aNanolab$$eDESY NanoLab: Sample Preparation$$x0
000631049 693__ $$0EXP:(DE-H253)Nanolab-02-20150101$$1EXP:(DE-H253)DESY-NanoLab-20150101$$5EXP:(DE-H253)Nanolab-02-20150101$$aNanolab$$eDESY NanoLab: Surface Spectroscopy$$x1
000631049 693__ $$0EXP:(DE-H253)Nanolab-03-20150101$$1EXP:(DE-H253)DESY-NanoLab-20150101$$5EXP:(DE-H253)Nanolab-03-20150101$$aNanolab$$eDESY NanoLab: X-Ray Diffraction$$x2
000631049 693__ $$0EXP:(DE-H253)P-P01-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P01-20150101$$aPETRA III$$fPETRA Beamline P01$$x3
000631049 7001_ $$0P:(DE-H253)PIP1033529$$aSchober, Jan-Christian$$b1$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1017841$$aCreutzburg, Marcus$$b2$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1090045$$aBeck, Esko Erik$$b3$$udesy
000631049 7001_ $$0P:(DE-HGF)0$$aSemione, Guilherme Dalla Lana$$b4
000631049 7001_ $$0P:(DE-H253)PIP1082934$$aChung, Simon$$b5$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1085323$$aJacobse, Leon$$b6
000631049 7001_ $$0P:(DE-H253)PIP1019785$$aArndt, Bjoern$$b7
000631049 7001_ $$0P:(DE-HGF)0$$aVlad, Alina$$b8
000631049 7001_ $$0P:(DE-H253)PIP1014894$$aSteinbrügge, René$$b9
000631049 7001_ $$0P:(DE-H253)PIP1006032$$aWille, Hans-Christian$$b10$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1016663$$aSergeev, Ilya$$b11$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1018647$$aNoei, Heshmat$$b12$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1005914$$aSchlage, Kai$$b13$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1002084$$aLeupold, Olaf$$b14$$udesy
000631049 7001_ $$0P:(DE-H253)PIP1013931$$aVonk, Vedran$$b15$$eCorresponding author
000631049 7001_ $$0P:(DE-H253)PIP1012873$$aStierle, Andreas$$b16$$eCorresponding author
000631049 773__ $$0PERI:(DE-600)1472655-5$$a10.1103/PhysRevLett.134.236203$$gVol. 134, no. 23, p. 236203$$n23$$p236203$$tPhysical review letters$$v134$$x0031-9007$$y2025
000631049 8564_ $$uhttps://journals.aps.org/prl/abstract/10.1103/PhysRevLett.134.236203
000631049 8564_ $$uhttps://bib-pubdb1.desy.de/record/631049/files/PhysRevLett.134.236203.pdf$$yOpenAccess
000631049 8564_ $$uhttps://bib-pubdb1.desy.de/record/631049/files/PhysRevLett.134.236203.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000631049 909CO $$ooai:bib-pubdb1.desy.de:631049$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1030341$$aDeutsches Elektronen-Synchrotron$$b0$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1033529$$aDeutsches Elektronen-Synchrotron$$b1$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1017841$$aDeutsches Elektronen-Synchrotron$$b2$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1090045$$aDeutsches Elektronen-Synchrotron$$b3$$kDESY
000631049 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$aExternal Institute$$b4$$kExtern
000631049 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1082934$$aExternal Institute$$b5$$kExtern
000631049 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1085323$$aExternal Institute$$b6$$kExtern
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1019785$$aDeutsches Elektronen-Synchrotron$$b7$$kDESY
000631049 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$aExternal Institute$$b8$$kExtern
000631049 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1014894$$aExternal Institute$$b9$$kExtern
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1006032$$aDeutsches Elektronen-Synchrotron$$b10$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1016663$$aDeutsches Elektronen-Synchrotron$$b11$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1018647$$aDeutsches Elektronen-Synchrotron$$b12$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1005914$$aDeutsches Elektronen-Synchrotron$$b13$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1002084$$aDeutsches Elektronen-Synchrotron$$b14$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1013931$$aDeutsches Elektronen-Synchrotron$$b15$$kDESY
000631049 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1012873$$aDeutsches Elektronen-Synchrotron$$b16$$kDESY
000631049 9131_ $$0G:(DE-HGF)POF4-632$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vMaterials – Quantum, Complex and Functional Materials$$x0
000631049 9141_ $$y2025
000631049 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)1230$$2StatID$$aDBCoverage$$bCurrent Contents - Electronics and Telecommunications Collection$$d2024-12-21
000631049 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000631049 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000631049 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-12-21
000631049 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2024-12-21$$wger
000631049 915__ $$0StatID:(DE-HGF)0571$$2StatID$$aDBCoverage$$bSCOAP3 sponsored Journal$$d2024-12-21
000631049 9201_ $$0I:(DE-H253)FS-NL-20120731$$kFS-NL$$lNanolab$$x0
000631049 9201_ $$0I:(DE-H253)FS-PETRA-S-20210408$$kFS-PETRA-S$$lPETRA-S$$x1
000631049 980__ $$ajournal
000631049 980__ $$aVDB
000631049 980__ $$aUNRESTRICTED
000631049 980__ $$aI:(DE-H253)FS-NL-20120731
000631049 980__ $$aI:(DE-H253)FS-PETRA-S-20210408
000631049 9801_ $$aFullTexts