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| 001 | 630460 | ||
| 005 | 20250723105959.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jlumin.2025.121333 |2 doi |
| 024 | 7 | _ | |a 0022-2313 |2 ISSN |
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| 100 | 1 | _ | |a Rebrova, Nadiia |0 P:(DE-H253)PIP1111484 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Pr$^{3+}$-doped RbCaF$_3$: a new X-ray-induced UVC persistent phosphor |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2025 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a The development of persistent ultraviolet-emitting phosphors is advancing rapidly because of their promisingapplications in alternative cancer treatments. In this work, we developed a novel Pr$^{3+}$-doped RbCaF3 phosphorexhibiting intense long-persistent luminescence in the 220–340 nm range, sustained for more than an hour afterjust 15 min of X-ray irradiation. The 5d-4f luminescence of Pr$^{3+}$ ions is primarily excited by electron-hole pairsgenerated during X-ray absorption, as well as by electrons released from traps. The emission and excitationproperties of RbCaF$_3$:Pr$^{3+}$ crystallites were further investigated using synchrotron radiation, revealing thesimultaneous occurrence of intra-configurational 4f$^2$→4f$^2$ and inter-configurational 4f5d → 4f$^2$ radiative tran-sitions upon 4f5d state excitation. This work highlights the potential of Pr$^{3+}$-doped RbCaF$_3$ phosphor forinnovative applications in ultraviolet photonics and cancer therapy. |
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| 700 | 1 | _ | |a Pushak, Andriy |0 P:(DE-H253)PIP1011539 |b 1 |
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| 700 | 1 | _ | |a Dereń, Przemysław J. |0 P:(DE-HGF)0 |b 6 |
| 773 | _ | _ | |a 10.1016/j.jlumin.2025.121333 |g Vol. 286, p. 121333 - |0 PERI:(DE-600)1491401-3 |p 121333 |t Journal of luminescence |v 286 |y 2025 |x 0022-2313 |
| 856 | 4 | _ | |u https://www.sciencedirect.com/science/article/pii/S002223132500273X |
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