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000630460 1001_ $$0P:(DE-H253)PIP1111484$$aRebrova, Nadiia$$b0$$eCorresponding author
000630460 245__ $$aPr$^{3+}$-doped RbCaF$_3$: a new X-ray-induced UVC persistent phosphor
000630460 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2025
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000630460 520__ $$aThe development of persistent ultraviolet-emitting phosphors is advancing rapidly because of their promisingapplications in alternative cancer treatments. In this work, we developed a novel Pr$^{3+}$-doped RbCaF3 phosphorexhibiting intense long-persistent luminescence in the 220–340 nm range, sustained for more than an hour afterjust 15 min of X-ray irradiation. The 5d-4f luminescence of Pr$^{3+}$ ions is primarily excited by electron-hole pairsgenerated during X-ray absorption, as well as by electrons released from traps. The emission and excitationproperties of RbCaF$_3$:Pr$^{3+}$ crystallites were further investigated using synchrotron radiation, revealing thesimultaneous occurrence of intra-configurational 4f$^2$→4f$^2$ and inter-configurational 4f5d → 4f$^2$ radiative tran-sitions upon 4f5d state excitation. This work highlights the potential of Pr$^{3+}$-doped RbCaF$_3$ phosphor forinnovative applications in ultraviolet photonics and cancer therapy.   
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000630460 7001_ $$0P:(DE-H253)PIP1011539$$aPushak, Andriy$$b1
000630460 7001_ $$0P:(DE-HGF)0$$aGrippa, Alexander$$b2
000630460 7001_ $$0P:(DE-H253)PIP1109249$$aBoiko, Vitalii$$b3
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000630460 7001_ $$0P:(DE-HGF)0$$aVoloshinovskii, Anatoliy$$b5
000630460 7001_ $$0P:(DE-HGF)0$$aDereń, Przemysław J.$$b6
000630460 773__ $$0PERI:(DE-600)1491401-3$$a10.1016/j.jlumin.2025.121333$$gVol. 286, p. 121333 -$$p121333 $$tJournal of luminescence$$v286$$x0022-2313$$y2025
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