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@ARTICLE{Strati:629254,
author = {Strati, Fabio and Drescher, Simon and Shen, Chen and
Neubert, Reinhard H. H. and Brezesinski, Gerald},
title = {{H}ydrogenated plant-based lecithins as excipients for
cosmetic and pharmaceutical applications: {A}
physical-chemical study},
journal = {European journal of pharmaceutical sciences},
volume = {211},
issn = {0928-0987},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {PUBDB-2025-01782},
pages = {107144},
year = {2025},
abstract = {Lecithin is a generic term that is often used to indicate a
product mainly constituted of phospholipids. Lecithins can
be used in pharmaceutical and cosmetic field as wetting
agents, emulsifiers and building blocks for the production
of liposomes and micelles. One of its main sources are
plants. From their extraction a final product mainly
constituted of phosphatidylcholines and
phosphatidylethanolamines can be obtained. Common issue
connected to freshly extracted lecithins is the presence of
a product rich in double bonds subject to photo and air
oxidation. By adding in the purification process a further
catalytic step, it is possible to form stable hydrogenated
lecithin products. Despite their widespread use, little is
known about the physicochemical properties of such
hydrogenated lecithins, detailed studies mainly based on
X-ray scattering methods on mono- and multi-layers have been
performed. Additionally, the emulsifying properties of these
lecithins such as Hydrophilic-Lipophilic Deviation (HLD
parameter) and solubility have also been studied. General
findings are that mixtures with higher amounts of
phosphatidylcholines (90–100 $\%)$ formed a well-defined
lamellar phase showing in monolayers complete absence of
charge, while lecithins with lower phosphatidylcholine
contents (75–80 $\%)$ formed charged monolayers and
positionally uncorrelated bilayers due to the presence of
charged species. The hydrogenated phospholipids (PLs)
studied were highly soluble in several co-solvents which are
suitable for the incorporation of these phospholipids into
relevant dermal formulations. The studied PLs are able to
stabilize innovative dermal colloidal formulations such as
cerosomes and to improve the incorporation of them into
Stratum corneum models.In conclusion, the following studies
will allow a more rational selection of hydrogenated
lecithins for the formulation of cosmetic and pharmaceutical
products.},
cin = {FS DOOR-User / FS-PET-D},
ddc = {610},
cid = {$I:(DE-H253)FS_DOOR-User-20241023$ /
I:(DE-H253)FS-PET-D-20190712},
pnm = {633 - Life Sciences – Building Blocks of Life: Structure
and Function (POF4-633) / 6G3 - PETRA III (DESY) (POF4-6G3)
/ FS-Proposal: I-20190800 (I-20190800)},
pid = {G:(DE-HGF)POF4-633 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20190800},
experiment = {EXP:(DE-H253)P-P08-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {40425131},
UT = {WOS:001504428300001},
doi = {10.1016/j.ejps.2025.107144},
url = {https://bib-pubdb1.desy.de/record/629254},
}