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@ARTICLE{Fang:627900,
      author       = {Fang, Wenting and Zhang, Yuyan and Kang, Liqun and DeBeer,
                      Serena and Leitner, Walter and Bordet, Alexis and Riisager,
                      Anders},
      title        = {{M}olecularly modified aluminum phosphates as support
                      materials for {R}u nanoparticles in selective hydrogenation},
      journal      = {Journal of catalysis},
      volume       = {442},
      issn         = {0021-9517},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2025-01675},
      pages        = {115911},
      year         = {2025},
      abstract     = {Modified aluminum phosphate (APO-5) proved suitable as
                      zeotype support for the preparation of imidazolium-based
                      supported ionic liquid phase material, i.e. SILP(APO-5). The
                      successful chemisorption of ionic liquid-like modifiers at
                      the APO-5 surface was demonstrated by solid- state $^{31}$P
                      and $^{13}$C nuclear magnetic resonance (NMR) spectroscopy.
                      The immobilization of Ru nanoparticles (NPs) on SILP(APO-5)
                      was achieved following an organometallic approach, producing
                      well-dispersed Ru NPs with a mean average size of 1.4 nm on
                      the support. The resulting Ru@SILP(APO-5) material was
                      thoroughly characterized using multiple techniques, e.g.,
                      solid-state NMR, transmission electron microscopy (TEM),
                      infrared (IR) spectroscopy, X-ray absorption spectroscopy
                      (XAS), and applied as a catalyst for the hydrogenation of
                      biomass-derived furfural acetone with molecular hydrogen.
                      The ionic liquid-like layer was found beneficial for the
                      stabilization of the Ru NPs as well as of the APO-5
                      material. A temperature-controlled selectivity switch
                      between olefinic, carbonyl or furan ring hydrogenation could
                      be achieved with this new material with the APO-5
                      facilitating activation of the olefinic bond, while the
                      carbonyl bond was remarkably deactivated. The demonstrated
                      suitability of aluminum phosphate materials to produce
                      molecularly modified surfaces offers a new control parameter
                      for the systematic design and optimization of zeotype-based
                      catalysts.},
      cin          = {FS DOOR-User},
      ddc          = {540},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / DFG project
                      G:(GEPRIS)390919832 - EXC 2186: Das Fuel Science Center –
                      Adaptive Umwandlungssysteme für erneuerbare Energie- und
                      Kohlenstoffquellen (390919832)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(GEPRIS)390919832},
      experiment   = {EXP:(DE-H253)P-P65-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001403087400001},
      doi          = {10.1016/j.jcat.2024.115911},
      url          = {https://bib-pubdb1.desy.de/record/627900},
}