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@ARTICLE{DalMolin:627891,
      author       = {Dal Molin, Emiliano S. and Javed, Mudassar and Brösigke,
                      Georg and Rudolph, Maik Alexander and Repke, Jens-Uwe and
                      Schomäcker, Reinhard and Simon, Ulla and Bekheet, Maged F.
                      and Gurlo, Aleksander},
      title        = {{A}dditively {M}anufactured {Z}irconia-{S}upported {I}ndium
                      {O}xide {C}atalysts and {T}heir {P}erformance in {D}irect
                      {M}ethanol {S}ynthesis},
      journal      = {Industrial $\&$ engineering chemistry research},
      volume       = {64},
      number       = {2},
      issn         = {0888-5885},
      address      = {Columbus, Ohio},
      publisher    = {American Chemical Society},
      reportid     = {PUBDB-2025-01666},
      pages        = {1032 - 1045},
      year         = {2025},
      abstract     = {In$_2$O$_3$/ZrO$_2$-based materials are emerging as
                      candidates for the next generation of industrial catalysts
                      for direct methanol synthesis. In this research, such
                      catalysts were additively manufactured into two distinct
                      geometries that exhibit different pressure drops and
                      activity profiles, both among themselves and in comparison
                      to extrudates. The monoliths produced were comprehensively
                      characterized using a range of techniques, including gas
                      sorption, X-ray diffraction, micro X-ray fluorescence, and
                      Raman mapping, to verify their phase and chemical
                      composition. Computational fluid dynamics was employed to
                      simulate the gas flow through these structures,
                      corroborating that the variations in the accessible surface
                      area are the reason for changes in their performance.
                      Furthermore, the postreaction characterization provides some
                      insight into the catalysts’ degradation mechanisms under
                      hydrogen-rich conditions, identifying the migration of
                      indium oxide to the catalyst surface and pore blocking as
                      possible causes of the loss of activity.},
      cin          = {FS DOOR-User},
      ddc          = {660},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / DFG project
                      G:(GEPRIS)390540038 - EXC 2008: Unifying Systems in
                      Catalysis "UniSysCat" (390540038) / FS-Proposal: II-20210010
                      (II-20210010) / FS-Proposal: I-20220620 (I-20220620)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(GEPRIS)390540038 /
                      G:(DE-H253)II-20210010 / G:(DE-H253)I-20220620},
      experiment   = {EXP:(DE-H253)P-P02.2-20150101 /
                      EXP:(DE-H253)P-P64-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001389937400001},
      doi          = {10.1021/acs.iecr.4c03439},
      url          = {https://bib-pubdb1.desy.de/record/627891},
}