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@ARTICLE{ISLAM:627002,
author = {ISLAM, MIJANUL and Adhikari, Sanat Kumar and Adhikari, Soma
and Chatterjee, Souvik and Goswami, S and De, Debajyoti and
Irshad, K. A. and Joseph, B. and Caliebe, Wolfgang and
Karmakar, Arindam},
title = {{C}harge conduction and relaxation in
{C}a$_{1−x}${D}y$_x${B}a{F}e$_4${O}$_7$},
journal = {Physical review / B},
volume = {111},
number = {5},
issn = {2469-9950},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {PUBDB-2025-01527},
pages = {054110},
year = {2025},
abstract = {The paper presents in-depth studies of the dielectric
properties and conduction dynamics of Dy-doped
CaBaFe$_4$O$_7$ which is a recently characterized
magnetoelectric material with strong potentials for
technological applications as it shows a
near-room-temperature ferrimagnetic transition along with
strong ferrimagnetic moment, and gigantic electric
polarization change. This work demonstrates the direct
correlation of the dielectric and electrical transport
properties of Ca$_{1−𝑥}$Dy$_𝑥$BaFe$_4$O$_7$
(𝑥=0, 0.01, 0.03, and 0.05) with structural distortion
through various dc, ac conduction, high-energy x-ray
diffraction studies, and modeling of the data.
CaBaFe$_4$O$_7$ has a unique structure characterized by
alternate stacking of FeO4 tetrahedra in triangular and
kagomé layers. Large structural distortion, competing
magnetic interactions, exchange striction effects, and
possible charge ordering are expected to play a major role
in the dielectric and electrical properties of the material.
We report observation of short-range polaron hopping
conduction mechanism in the low-temperature regime and
signature of large polaronic nature of charge carriers.
Modeling of the electric modulus using Havriliak-Negami
equation points out both distribution and cooperativeness in
the polaron dynamics which can be correlated to the
interplay of structural distortion, and the background
electric field due to the polar nature of the materials. The
Havriliak-Negami parameters closely follow orthorhombic
distortion of the structures.},
cin = {DOOR ; HAS-User / FS-PET-S},
ddc = {530},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PET-S-20190712},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
FS-Proposal: I-20210617 (I-20210617)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20210617},
experiment = {EXP:(DE-H253)P-P64-20150101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001447739000003},
doi = {10.1103/PhysRevB.111.054110},
url = {https://bib-pubdb1.desy.de/record/627002},
}