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000626264 1001_ $$0P:(DE-H253)PIP1103005$$aMorag, Ahiud$$b0
000626264 245__ $$aUnlocking Four‐electron Conversion in Tellurium Cathodes for Advanced Magnesium‐based Dual‐ion Batteries
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000626264 520__ $$aMagnesium (Mg) batteries hold promise as a large-scale energy storage solution, but their progress has been hindered by the lack of high-performance cathodes. Here, we address this challenge by unlocking the reversible four-electron Te$^0$/Te$^{4+}$ conversion in elemental Te, enabling the demonstration of superior Mg//Te dual-ion batteries. Specifically, the classic magnesium aluminum chloride complex (MACC) electrolyte is tailored by introducing Mg bis(trifluoromethanesulfonyl)imide (Mg(TFSI)$_2$), which initiates the Te$^0$/Te$^{4+}$ conversion with two distinct charge-storage steps. Te cathode undergoes Te/TeCl$_4$ conversion involving Cl− as charge carriers, during which a tellurium subchloride phase is presented as an intermediate. Significantly, the Te cathode achieves a high specific capacity of 543 mAh gTe$^{−1}$ and an outstanding energy density of 850 Wh kgTe$^{−1}$, outperforming most of the previously reported cathodes. Our electrolyte analysis indicates that the addition of Mg(TFSI)2 reduces the overall ion-molecule interaction and mitigates the strength of ion-solvent aggregation within the MACC electrolyte, which implies the facilized Cl− dissociation from the electrolyte. Besides, Mg(TFSI)$_2$ is verified as an essential buffer to mitigate the corrosion and passivation of Mg anodes caused by the consumption of the electrolyte MgCl$_2$ in Mg//Te dual-ion cells. These findings provide crucial insights into the development of advanced Mg-based dual-ion batteries. 
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000626264 7001_ $$0P:(DE-H253)PIP1101476$$aChu, Xingyuan$$b1
000626264 7001_ $$aMarczewski, Maciej$$b2
000626264 7001_ $$aKunigkeit, Jonas$$b3
000626264 7001_ $$aNeumann, Christof$$b4
000626264 7001_ $$aSabaghi, Davood$$b5
000626264 7001_ $$aŻukowska, Grażyna Zofia$$b6
000626264 7001_ $$0P:(DE-H253)PIP1098080$$aDu, Jingwei$$b7
000626264 7001_ $$0P:(DE-H253)PIP1080044$$aLi, Xiaodong$$b8
000626264 7001_ $$aTurchanin, Andrey$$b9
000626264 7001_ $$aBrunner, Eike$$b10
000626264 7001_ $$0P:(DE-H253)PIP1081776$$aFeng, Xinliang$$b11$$eCorresponding author
000626264 7001_ $$0P:(DE-H253)PIP1083931$$aYu, Minghao$$b12$$eCorresponding author
000626264 773__ $$0PERI:(DE-600)2011836-3$$a10.1002/anie.202401818$$gVol. 63, no. 19, p. e202401818$$n19$$pe202401818$$tAngewandte Chemie / International edition$$v63$$x1433-7851$$y2024
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