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@ARTICLE{Konowski:626254,
      author       = {Konowski, Kai and Bon, Volodymyr and Karlsen, Martin A. and
                      Etter, Martin and Bönisch, Nadine and De, Ankita and
                      Kaskel, Stefan},
      title        = {{P}robing the {L}imits of {M}echanical {S}tability of the
                      {M}esoporous {M}etal–{O}rganic {F}ramework {DUT}-76({C}u)
                      by {H}ydrocarbon {P}hysisorption},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {17},
      number       = {16},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PUBDB-2025-01337},
      pages        = {24096 - 24105},
      year         = {2025},
      abstract     = {The mechanical robustness of MOFs is crucial in most
                      adsorption-related applications. Herein, we investigated the
                      interaction of the mesoporous metal–organic framework
                      DUT-76(Cu) with various C1–C4 hydrocarbons at their
                      boiling points. During adsorption, the pore structure
                      partially collapsed into an amorphous phase while retaining
                      a residual porosity. We employed a combination of multicycle
                      physisorption experiments using different hydrocarbons
                      (methane, ethane, ethylene, propane, propylene, n-butane,
                      and 1,3-butadiene) along with X-ray diffraction, scanning
                      electron microscopy, and total scattering to examine this
                      transition. This methodology allowed us to gain a
                      comprehensive understanding of the effects on the crystal
                      structure, local structure, and macroscopic behavior of the
                      material. Furthermore, we identified specific correlations
                      among the chain length, number of double bonds, and
                      adsorption/desorption cycle stability, which are influenced
                      by adsorption-induced stress. These multicycle adsorption
                      experiments served as semiquantitative tools for assessing
                      the mechanical stability of mesoporous frameworks.},
      cin          = {FS DOOR-User / FS-PET-D},
      ddc          = {600},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$ /
                      I:(DE-H253)FS-PET-D-20190712},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: I-20220986 (I-20220986) / 05K22OD1 -
                      Instrumentierung für zeitaufgelöste
                      röntgenpulverdiffraktometrische Untersuchungen von
                      adsorptionsinduziertem Schalten in kristallinen nanoporösen
                      Materialien (BMBF-05K22OD1) / 05K22OD2 - Verbundprojekt
                      05K2022 - TOMOPORE: Multizweck Instrumentierung für das
                      Monitoring von Fluiddynamik in nanoporösen Feststoffen
                      mittels in situ Röntgenkryotomographie und
                      röntgenspektroskopischen Methoden. Teilprojekt 1.
                      (BMBF-05K22OD2)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)I-20220986 / G:(DE-Ds200)BMBF-05K22OD1 /
                      G:(DE-Ds200)BMBF-05K22OD2},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {40196993},
      UT           = {WOS:001462049500001},
      doi          = {10.1021/acsami.5c00164},
      url          = {https://bib-pubdb1.desy.de/record/626254},
}