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@ARTICLE{Jin:626253,
      author       = {Jin, Eunji and Bon, Volodymyr and Das, Shubhajit and
                      Wonanke, A. D. Dinga and Etter, Martin and Karlsen, Martin
                      A. and De, Ankita and Bönisch, Nadine and Heine, Thomas and
                      Kaskel, Stefan},
      title        = {{E}ngineering {P}hotoswitching {D}ynamics in 3{D}
                      {P}hotochromic {M}etal–{O}rganic {F}rameworks through a
                      {M}etal–{O}rganic {P}olyhedron {D}esign},
      journal      = {Journal of the American Chemical Society},
      volume       = {147},
      number       = {10},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {PUBDB-2025-01336},
      pages        = {8568 - 8577},
      year         = {2025},
      abstract     = {Metal–organic polyhedra (MOPs) are versatile
                      supramolecular building blocks for the design of highly
                      porous frameworks by reticular assembly because of their
                      diverse geometries, multiple degrees of freedom regarding
                      functionalization, and accessible metal sites. Lipophilic
                      functionalization is demonstrated to enable the rational
                      assembly and crystallization with photoactive N-donor
                      ligands in an aliphatic solvent to achieve multiaxially
                      aligned photoresponsive diarylethene (DTE) moieties in 3D
                      frameworks (DUT-210(M), M = Cu and Rh) featuring cooperative
                      switchability. Combined experimental and theoretical
                      investigations based on in situ PXRD, UV–vis spectroscopy,
                      and density functional theory calculations demonstrate
                      deliberate kinetic engineering of photoswitchability based
                      on variations in metal–ligand bond strengths. The novel
                      porous frameworks are an important step toward the
                      knowledge-based development of photon-driven motors,
                      actuators, and release systems.},
      cin          = {FS DOOR-User / FS-PET-D},
      ddc          = {540},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$ /
                      I:(DE-H253)FS-PET-D-20190712},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: I-20220986 (I-20220986) / FlexiMOFs-2 - A
                      Design Principle for Prediting Flexible Metal-Organic
                      Frameworks (101107360)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)I-20220986 / G:(EU-Grant)101107360},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39995312},
      UT           = {WOS:001432838700001},
      doi          = {10.1021/jacs.4c17203},
      url          = {https://bib-pubdb1.desy.de/record/626253},
}