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@ARTICLE{Striker:626048,
author = {Striker, Nele and Krywka, Christina and Goy, Claudia and
Hoevelmann, Svenja Carolin and Giesselmann, Niels Christian
and Schulz, Florian and Lokteva, Irina and Westermeier,
Fabian and Caupin, Frederic and Paulus, Michael and
Lehmkühler, Felix},
title = {{P}hase behavior of {S}ilica-{PNIPA}m nanogels under high
hydrostatic pressure},
journal = {Journal of applied crystallography},
volume = {58},
number = {3},
issn = {0021-8898},
address = {Copenhagen},
publisher = {Munksgaard},
reportid = {PUBDB-2025-01270},
pages = {919 - 926},
year = {2025},
abstract = {The structure and dynamics of concentrated silica-PNIPAm
nanogels are studied as a function of hydrostatic pressure
up to 3500 bar. A combination of X-ray photon correlation
spectroscopy and small-angle X-ray scattering shows similar
characteristics of the dynamics for both temperature- and
pressure-induced volume phase transitions of PNIPAm
nanogels. Upon increasing the pressure and depending on the
initial particle volume fraction, a transition from a liquid
or glass state to a colloidal gel is observed for pressures
$p \approx 1500$ bar at a temperature of 293 K.
Time-dependent analysis of the dynamics shows ageing in
glass and gel samples which is absent in the liquid state.
This indicates stress-dominated dynamics upon pressure
changes that equilibrate after few 100 s.},
cin = {FS-SMP / FS-PETRA-S / Hereon / DOOR ; HAS-User},
ddc = {540},
cid = {I:(DE-H253)FS-SMP-20171124 / I:(DE-H253)FS-PETRA-S-20210408
/ I:(DE-H253)Hereon-20210428 / I:(DE-H253)HAS-User-20120731},
pnm = {633 - Life Sciences – Building Blocks of Life: Structure
and Function (POF4-633) / 6G3 - PETRA III (DESY) (POF4-6G3)
/ AIM, DFG project G:(GEPRIS)390715994 - EXC 2056: CUI:
Advanced Imaging of Matter (390715994) / FS-Proposal:
I-20221104 EC (I-20221104-EC)},
pid = {G:(DE-HGF)POF4-633 / G:(DE-HGF)POF4-6G3 /
G:(GEPRIS)390715994 / G:(DE-H253)I-20221104-EC},
experiment = {EXP:(DE-H253)P-P10-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1107/S1600576725003188},
url = {https://bib-pubdb1.desy.de/record/626048},
}