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@ARTICLE{Huber:625356,
      author       = {Huber, Linus and Sun, Kun and Reus, Manuel A. and Weindl,
                      Christian L. and Heger, Julian E. and Roth, Stephan V. and
                      Mueller-Buschbaum, Peter},
      title        = {{B}eta‐{L}actoglobulin for {W}ater‐{B}ased and
                      {T}unable {N}anostructure {T}emplating of {P}rinted
                      {T}itania {T}hin {F}ilms: {T}he {I}nfluence of p{H} {V}alue
                      and {P}rotein {C}oncentration},
      journal      = {Advanced materials interfaces},
      volume       = {12},
      number       = {13},
      issn         = {2196-7350},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2025-01113},
      pages        = {2400929},
      year         = {2025},
      abstract     = {An environmentally friendly as well as scalable synthesis
                      route of nanostructured titania thin films is of interest
                      for many state-of-the-art devices, from solar cells to
                      battery materials. Beta-lactoglobulin (ß-lg) enables
                      water-based and tunable titania thin film templating,
                      allowing for different domain sizes, porosities, and
                      morphologies. When printed with a slot-die coater, the
                      titania films can be tailored to specific applications with
                      simple changes to the solution chemistry. Films printed at
                      acidic pH conditions form significantly different final
                      morphologies than films printed at a neutral pH value. The
                      protein concentration plays a more limited role in the final
                      nanostructure. With in situ grazing incidence
                      small-angle/wide-angle X-ray scattering (GISAXS/GIWAXS), the
                      structure formation is followed with an excellent time
                      resolution during the printing process. From the GISAXS
                      measurements, the size evolution of the titania clusters is
                      understood, showing significant differences for different pH
                      values. Crystal phases and corresponding crystal
                      orientations are investigated with GIWAXS. The combination
                      of a water-based titania synthesis with the scalable film
                      deposition via slot die coating makes the presented results
                      interesting for potential environmentally friendly mass
                      production of nanostructured titania films.},
      cin          = {DOOR ; HAS-User / FS-SMA},
      ddc          = {600},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-SMA-20220811},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      DFG project G:(GEPRIS)390776260 - EXC 2089: e-conversion
                      (390776260) / 05D23WO1 - Verbundprojekt 05D2022 - VIPR:
                      Vielseitiges Software Framework zur Lösung Inverser
                      Probleme. Teilprojekt 5. (BMBF-05D23WO1)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(GEPRIS)390776260 / G:(DE-Ds200)BMBF-05D23WO1},
      experiment   = {EXP:(DE-H253)P-P03-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1002/admi.202400929},
      url          = {https://bib-pubdb1.desy.de/record/625356},
}