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@ARTICLE{Gholami:625354,
      author       = {Gholami, Shirin and Buttersack, Tillmann and Richter,
                      Clemens and Trinter, Florian and Dupuy, Remi and Cablitz,
                      Louisa and Zhou, Qi and nicolas, christophe and Shavorskiy,
                      Andrey and Diaman, Dian and Hergenhahn, Uwe and Winter,
                      Bernd and Bluhm, Hendrik},
      title        = {{I}nteraction of ions and surfactants at the seawater–air
                      interface},
      journal      = {Environmental science / Atmospheres},
      volume       = {5},
      number       = {3},
      issn         = {2634-3606},
      address      = {Cambridge},
      publisher    = {Royal Society of Chemistry},
      reportid     = {PUBDB-2025-01111},
      pages        = {291 - 299},
      year         = {2025},
      abstract     = {The interface of the oceans and aqueous aerosols with air
                      drives many important physical and chemical processes in the
                      environment, including the uptake of CO2 by the oceans.
                      Transport across and reactions at the ocean–air boundary
                      are in large part determined by the chemical composition of
                      the interface, i.e., the first few nanometers into the
                      ocean. The main constituents of the interface, besides water
                      molecules, are dissolved ions and amphiphilic surfactants,
                      which are ubiquitous in nature. We have used a combination
                      of surface tension measurements and liquid-jet X-ray
                      photoelectron spectroscopy to investigate model seawater
                      solutions at realistic ocean-water ion concentrations in the
                      absence and in the presence of model surfactants. Our
                      investigations provide a quantitative picture of the
                      enhancement or reduction of the concentration of ions due to
                      the presence of charged surfactants at the interface. We
                      have also directly determined the concentration of
                      surfactants at the interface, which is related to the ionic
                      strength of the solution (i.e., the “salting out”
                      effect). Our results show that the interaction of ions and
                      surfactants can strongly change the concentration of both
                      classes of species at aqueous solution–air interfaces,
                      with direct consequences for heterogeneous reactions as well
                      as gas uptake and release at ocean–air interfaces.},
      cin          = {DOOR ; HAS-User / FS-PS / FS-PET-S},
      ddc          = {333.7},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-PS-20131107 /
                      I:(DE-H253)FS-PET-S-20190712},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: I-20221212 (I-20221212) / DFG project
                      G:(GEPRIS)509471550 - Dynamik photoionisations-induzierter
                      Prozesse in laser-präparierten Molekülen in der Gasphase
                      und der wässrigen Phase (509471550) / AQUACHIRAL - Chiral
                      aqueous-phase chemistry (883759)},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)I-20221212 / G:(GEPRIS)509471550 /
                      G:(EU-Grant)883759},
      experiment   = {EXP:(DE-H253)P-P04-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39989667},
      UT           = {WOS:001426902700001},
      doi          = {10.1039/D4EA00151F},
      url          = {https://bib-pubdb1.desy.de/record/625354},
}