Home > Publications database > Characterization of the Spin-Frustration in Doubly Ordered Perovskite NaYbZnWO$_6$ Obtained by High-Pressure Synthesis > print

001     625325
005     20250715151518.0
024 7 _ |a 10.1021/acs.inorgchem.4c04122
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100 1 _ |a Kumar, Rahul
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245 _ _ |a Characterization of the Spin-Frustration in Doubly Ordered Perovskite NaYbZnWO$_6$ Obtained by High-Pressure Synthesis
260 _ _ |a Washington, DC
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520 _ _ |a We present the high-pressure synthesis of a novel doubly ordered perovskite NaYbZnWO$_6$ composed of the rare earth magnetic Yb$^{3+}$ ions and its comprehensive magnetic characterization. The structure consists of alternating layers of Yb$^{3+}$ and Na$^+$ ions along the c-axis, with Yb$^{3+}$ ions forming slightly distorted two-dimensional (2D) square lattices of kite-shape (Yb$^{3+}$)4 units. Low-temperature magnetic susceptibility measurements indicate that the ground state of Yb$^{3+}$ can be described by an effective J$_{eff}$ = 1/2 Kramers doublet. Further, specific heat analysis reveals an internal magnetic field of the order of 1.48 K; however, magnetization data do not exhibit magnetic ordering down to 0.4 K. The spin exchanges of NaYbZnWO$_6$ evaluated by density functional theory (DFT) calculations unveil spin frustration in the compound. These findings suggest that NaYbZnWO$_6$ is a promising candidate for realizing a magnetically disordered quantum state.
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700 1 _ |a Bhat, Shrikant
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700 1 _ |a Koo, Hyun-Joo
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700 1 _ |a Nam, Kiwan
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700 1 _ |a Kim, Seong-Hoon
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700 1 _ |a Kim, Kee Hoon
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700 1 _ |a Whangbo, Myung-Hwan
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700 1 _ |a Athinarayanan, Sundaresan
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773 _ _ |a 10.1021/acs.inorgchem.4c04122
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856 4 _ |u https://bib-pubdb1.desy.de/record/625325/files/Full-paper.pdf
856 4 _ |y Published on 2025-02-13. Available in OpenAccess from 2026-02-13.
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