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@ARTICLE{Kumar:625325,
author = {Kumar, Rahul and Bhat, Shrikant and Koo, Hyun-Joo and Nam,
Kiwan and Kim, Seong-Hoon and Kim, Kee Hoon and Whangbo,
Myung-Hwan and Athinarayanan, Sundaresan},
title = {{C}haracterization of the {S}pin-{F}rustration in {D}oubly
{O}rdered {P}erovskite {N}a{Y}b{Z}n{WO}$_6$ {O}btained by
{H}igh-{P}ressure {S}ynthesis},
journal = {Inorganic chemistry},
volume = {64},
number = {8},
issn = {0020-1669},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {PUBDB-2025-01099},
pages = {3677 - 3685},
year = {2025},
abstract = {We present the high-pressure synthesis of a novel doubly
ordered perovskite NaYbZnWO$_6$ composed of the rare earth
magnetic Yb$^{3+}$ ions and its comprehensive magnetic
characterization. The structure consists of alternating
layers of Yb$^{3+}$ and Na$^+$ ions along the c-axis, with
Yb$^{3+}$ ions forming slightly distorted two-dimensional
(2D) square lattices of kite-shape (Yb$^{3+}$)4 units.
Low-temperature magnetic susceptibility measurements
indicate that the ground state of Yb$^{3+}$ can be described
by an effective J$_{eff}$ = 1/2 Kramers doublet. Further,
specific heat analysis reveals an internal magnetic field of
the order of 1.48 K; however, magnetization data do not
exhibit magnetic ordering down to 0.4 K. The spin exchanges
of NaYbZnWO$_6$ evaluated by density functional theory (DFT)
calculations unveil spin frustration in the compound. These
findings suggest that NaYbZnWO$_6$ is a promising candidate
for realizing a magnetically disordered quantum state.},
cin = {FS-PETRA-D / DOOR ; HAS-User},
ddc = {540},
cid = {I:(DE-H253)FS-PETRA-D-20210408 /
I:(DE-H253)HAS-User-20120731},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) /
FS-Proposal: I-20221028 (I-20221028) / FS-Proposal:
I-20210548 (I-20210548) / INDIA-DESY - INDIA-DESY
Collaboration $(2020_Join2-INDIA-DESY)$},
pid = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20221028 / G:(DE-H253)I-20210548 /
$G:(DE-HGF)2020_Join2-INDIA-DESY$},
experiment = {EXP:(DE-H253)P-P61.2-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:39949074},
UT = {WOS:001435957600001},
doi = {10.1021/acs.inorgchem.4c04122},
url = {https://bib-pubdb1.desy.de/record/625325},
}