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@ARTICLE{Karina:625242,
author = {Karina, Aigerim and Li, Hailong and Eklund, Tobias and
Ladd-Parada, Marjorie and Massani, Bernhard and Filianina,
Mariia and Kondedan, Neha and Rydh, Andreas and Holl, Klara
and Trevorah, Ryan and Huotari, Simo and Bauer, Robert and
Goy, Claudia and Striker, Nele and Dallari, Francesco and
Westermeier, Fabian and Sprung, Michael and Lehmkühler,
Felix and Amann-Winkel, Katrin},
title = {{M}ulticomponent dynamics in amorphous ice studied using
{X}-ray photon correlation spectroscopy at elevated pressure
and cryogenic temperatures},
journal = {Communications chemistry},
volume = {8},
number = {1},
issn = {2399-3669},
address = {[London]},
publisher = {Macmillan Publishers Limited, part of Springer Nature},
reportid = {PUBDB-2025-01058},
pages = {82},
year = {2025},
abstract = {Knowing the pressure dependence of glass forming liquids is
important in various contexts. Here, we study the case of
supercooled water, which has at least two different
amorphous states with different densities. The pressure
dependencies of the two glass transitions are predicted to
show opposite behaviour, crossing in the P-T plane at
elevated pressure. The experimental identification of the
glass transition at elevated pressure and cryo-conditions is
technically difficult. Moreover, in the case of amorphous
ices, the glass transition is interrupted by
crystallization, which makes it even more challenging. We
show the feasibility of performing X-ray photon correlation
spectroscopy experiments at elevated pressure using a
diamond anvil cell at cryogenic temperatures. We observe two
dynamic components when approaching the glass transition
temperature. For high-density amorphous ice at a pressure of
around (0.08 ± 0.02) GPa we determine the glass
transition to be at higher temperatures compared to ambient
conditions.},
cin = {DOOR ; HAS-User / FS-SMP / FS-PETRA-S / FS-CXS},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-SMP-20171124 /
I:(DE-H253)FS-PETRA-S-20210408 / I:(DE-H253)FS-CXS-20130727},
pnm = {633 - Life Sciences – Building Blocks of Life: Structure
and Function (POF4-633) / 6G3 - PETRA III (DESY) (POF4-6G3)
/ FS-Proposal: I-20200286 EC (I-20200286-EC) / FS-Proposal:
I-20220659 (I-20220659) / SWEDEN-DESY - SWEDEN-DESY
Collaboration $(2020_Join2-SWEDEN-DESY)$},
pid = {G:(DE-HGF)POF4-633 / G:(DE-HGF)POF4-6G3 /
G:(DE-H253)I-20200286-EC / G:(DE-H253)I-20220659 /
$G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
experiment = {EXP:(DE-H253)P-P10-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {40091131},
UT = {WOS:001445653700001},
doi = {10.1038/s42004-025-01480-8},
url = {https://bib-pubdb1.desy.de/record/625242},
}