% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{AlTayyem:624370,
      author       = {Al-Tayyem, Ban and Müscher-Polzin, Philipp and Pande,
                      Kanupriya and Yefanov, Oleksandr and Mariani, Valerio and
                      Burkhardt, Anja and Chapman, Henry N. and Näther, Christian
                      and Braun, Michael and Radke, Marvin and Waitschat, Steve
                      and Beyerlein, Kenneth and Terraschke, Huayna},
      title        = {{I}n situ monitoring of ligand-to-metal energy transfer in
                      combination with synchrotron-based {X}-ray diffraction
                      methods to elucidate the synthesis mechanism and structural
                      evolution of lanthanide complexes},
      journal      = {Frontiers in Chemistry},
      volume       = {13},
      issn         = {2296-2646},
      address      = {Lausanne},
      publisher    = {Frontiers Media},
      reportid     = {PUBDB-2025-00839},
      pages        = {1536383},
      year         = {2025},
      abstract     = {Despite wide application of lanthanide complexes in solar
                      cells, light-emitting diodes and sensors, their
                      crystallization mechanisms have not been studied in detail.
                      Further investigations of this kind can lead to the
                      development of targeted synthesis protocols and tailoring of
                      their structure-related physical properties. In this work,
                      the structural evolution during the synthesis of the
                      luminescent [Tb(bipy)2(NO3)3] (bipy = 2,2'-bipyridine)
                      complex is studied by monitoring the ligand-to-metal energy
                      transfer through in situ luminescence measurements combined
                      with synchrotron-based X-ray diffraction (XRD) analysis.
                      These experiments reveal an interesting crystallization
                      pathway involving the formation of a reaction intermediate
                      that is dependent on parameters such as ligand-to-metal
                      molar ratios. In addition, the structure of
                      [Tb(bipy)2(NO3)3] is solved from serial crystallography data
                      collected at a microfocused synchrotron X-ray beamline. This
                      is an emerging technique that can be used to interrogate
                      individual crystallites and overcome beam damage effects.
                      The resulting structure is found to correspond to that
                      determined by classical single crystal XRD, and a
                      perspective on realizing future in situ measurements of this
                      type is given. This work therefore describes multiple
                      advancements combining crystallite-specific diffraction
                      probes and in situ techniques to track the synthesis
                      kinetics of luminescent materials.},
      cin          = {CFEL-I / FS-PETRA-D},
      ddc          = {540},
      cid          = {I:(DE-H253)CFEL-I-20161114 /
                      I:(DE-H253)FS-PETRA-D-20210408},
      pnm          = {633 - Life Sciences – Building Blocks of Life: Structure
                      and Function (POF4-633) / AIM, DFG project
                      G:(GEPRIS)390715994 - EXC 2056: CUI: Advanced Imaging of
                      Matter (390715994) / FS-Proposal: I-20160643 (I-20160643) /
                      FS-Proposal: I-20160477 (I-20160477)},
      pid          = {G:(DE-HGF)POF4-633 / G:(GEPRIS)390715994 /
                      G:(DE-H253)I-20160643 / G:(DE-H253)I-20160477},
      experiment   = {EXP:(DE-H253)P-P11-20150101 / EXP:(DE-H253)P-P08-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:40313400},
      doi          = {10.3389/fchem.2025.1536383},
      url          = {https://bib-pubdb1.desy.de/record/624370},
}