000623850 001__ 623850
000623850 005__ 20250721115145.0
000623850 0247_ $$2arXiv$$aarXiv:2405.15367
000623850 0247_ $$2doi$$a10.1038/s41467-025-57083-3
000623850 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-00802
000623850 0247_ $$2altmetric$$aaltmetric:175059313
000623850 0247_ $$2pmid$$apmid:40021641
000623850 0247_ $$2WOS$$aWOS:001435592900010
000623850 0247_ $$2openalex$$aopenalex:W4408027852
000623850 037__ $$aPUBDB-2025-00802
000623850 041__ $$aEnglish
000623850 082__ $$a500
000623850 088__ $$2arXiv$$aarXiv:2405.15367
000623850 1001_ $$0P:(DE-H253)PIP1084564$$aJahnke, Till$$b0$$eCorresponding author
000623850 245__ $$aDirect observation of ultrafast symmetry reduction during internal conversion of 2-thiouracil using Coulomb explosion imaging
000623850 260__ $$a[London]$$bSpringer Nature$$c2025
000623850 3367_ $$2DRIVER$$aarticle
000623850 3367_ $$2DataCite$$aOutput Types/Journal article
000623850 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1741771690_1508630
000623850 3367_ $$2BibTeX$$aARTICLE
000623850 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000623850 3367_ $$00$$2EndNote$$aJournal Article
000623850 500__ $$a19 pages, 8 figures. Title is: Direct observation of ultrafast symmetry reduction during internal conversion 2-thiouracil using Coulomb explosion imagingBitte mit dem 
000623850 520__ $$aThe photochemistry of heterocyclic molecules plays a decisive role for processes and applications like DNA photo-protection from UV damage and organic photocatalysis. The photochemical reactivity of heterocycles is determined by the redistribution of photoenergy into electronic and nuclear degrees of freedom, initially involving ultrafast internal conversion. Most heterocycles are planar in their ground state and internal conversion requires symmetry breaking. To lower the symmetry, the molecule must undergo an out-of-plane motion, which has not yet been observed directly. Here we show using the example of 2-thiouracil, how Coulomb explosion imaging can be utilized to extract comprehensive information on this molecular deformation, linking the extracted deplanarization of the molecular geometry to the previously studied temporal evolution of its electronic properties. Particularly, the protons of the exploded molecule are well-suited messengers carrying rich information on its geometry at distinct times after electronic excitation. We expect that our new analysis approach centered on these peripheral protons can be adapted as a general concept for future time-resolved studies of complex molecules in the gas phase.
000623850 536__ $$0G:(DE-HGF)POF4-631$$a631 - Matter – Dynamics, Mechanisms and Control (POF4-631)$$cPOF4-631$$fPOF IV$$x0
000623850 536__ $$0G:(DE-HGF)POF4-6G2$$a6G2 - FLASH (DESY) (POF4-6G2)$$cPOF4-6G2$$fPOF IV$$x1
000623850 536__ $$0G:(GEPRIS)390715994$$aAIM, DFG project G:(GEPRIS)390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994)$$c390715994$$x2
000623850 536__ $$0G:(GEPRIS)509471550$$aDFG project G:(GEPRIS)509471550 - Dynamik photoionisations-induzierter Prozesse in laser-präparierten Molekülen in der Gasphase und der wässrigen Phase (509471550)$$c509471550$$x3
000623850 536__ $$0G:(EU-Grant)101067645$$a123-CO - Spying on Ultrafast Structural Changes Through Three Sets of Eyes (101067645)$$c101067645$$fHORIZON-MSCA-2021-PF-01$$x4
000623850 588__ $$aDataset connected to DataCite
000623850 693__ $$0EXP:(DE-H253)F-FL24-20150901$$1EXP:(DE-H253)FLASHII-20150901$$6EXP:(DE-H253)F-FL24-20150901$$aFLASH2$$fFLASH2 Beamline FL24$$x0
000623850 7001_ $$aMai, Sebastian$$b1
000623850 7001_ $$0P:(DE-H253)PIP1095450$$aBhattacharyya, Surjendu$$b2
000623850 7001_ $$0P:(DE-H253)PIP1099016$$aChen, Keyu$$b3
000623850 7001_ $$0P:(DE-H253)PIP1014282$$aBoll, Rebecca$$b4
000623850 7001_ $$0P:(DE-H253)PIP1103529$$aCastellani, Maria Elena$$b5
000623850 7001_ $$0P:(DE-H253)PIP1027431$$aDold, Simon$$b6
000623850 7001_ $$0P:(DE-H253)PIP1104549$$aDuley, Avijit$$b7
000623850 7001_ $$0P:(DE-H253)PIP1005343$$aFrühling, Ulrike$$b8
000623850 7001_ $$0P:(DE-H253)PIP1099247$$aGreen, Alice E.$$b9
000623850 7001_ $$0P:(DE-H253)PIP1007017$$aIlchen, Markus$$b10
000623850 7001_ $$0P:(DE-H253)PIP1031944$$aIngle, Rebecca$$b11
000623850 7001_ $$0P:(DE-H253)PIP1014655$$aKastirke, Gregor$$b12
000623850 7001_ $$0P:(DE-H253)PIP1099018$$aLam, Huynh Van Sa$$b13
000623850 7001_ $$aLever, Fabiano$$b14
000623850 7001_ $$0P:(DE-H253)PIP1087484$$aMayer, Dennis$$b15
000623850 7001_ $$0P:(DE-H253)PIP1013759$$aMazza, Tommaso$$b16
000623850 7001_ $$0P:(DE-H253)PIP1013728$$aMullins, Terence$$b17
000623850 7001_ $$0P:(DE-H253)PIP1014906$$aOvcharenko, Yevheniy$$b18
000623850 7001_ $$0P:(DE-H253)PIP1027397$$aSenfftleben, Björn$$b19
000623850 7001_ $$0P:(DE-H253)PIP1017364$$aTrinter, Florian$$b20
000623850 7001_ $$aNoor, Atia Tul$$b21
000623850 7001_ $$0P:(DE-H253)PIP1013098$$aUsenko, Sergey$$b22
000623850 7001_ $$0P:(DE-H253)PIP1096868$$aVenkatachalam, Anbu Selvam$$b23
000623850 7001_ $$0P:(DE-H253)PIP1006803$$aRudenko, Artem$$b24
000623850 7001_ $$0P:(DE-H253)PIP1007320$$aRolles, Daniel$$b25
000623850 7001_ $$aMeyer, Michael$$b26
000623850 7001_ $$0P:(DE-H253)PIP1103428$$aIbrahim, Heide$$b27
000623850 7001_ $$0P:(DE-H253)PIP1084094$$aGühr, Markus$$b28$$eCorresponding author
000623850 773__ $$0PERI:(DE-600)2553671-0$$a10.1038/s41467-025-57083-3$$gVol. 16, no. 1, p. 2074$$p2074$$tNature Communications$$v16$$x2041-1723$$y2025
000623850 7870_ $$0PUBDB-2025-01007$$aJahnke, Till et.al.$$d2025$$iIsParent$$rarXiv:2405.15367$$tX-ray Coulomb explosion imaging reveals role of molecular structure in internal conversion
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/Article%20Approval%20Service.pdf
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/HTML-Approval_of_scientific_publication.html
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/PDF-Approval_of_scientific_publication.pdf
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/Article%20Approval%20Service.pdf?subformat=pdfa$$xpdfa
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/s41467-025-57083-3.pdf$$yOpenAccess
000623850 8564_ $$uhttps://bib-pubdb1.desy.de/record/623850/files/s41467-025-57083-3.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000623850 8767_ $$92025-02-27$$d2025-02-27$$eAPC$$jDEAL$$lSpringerNature$$zRechnung SN-2025-00446-b
000623850 8767_ $$d2025-02-27$$eOther$$jDEAL$$lSpringerNature$$zMPDL Gebühr
000623850 8767_ $$92025-02-27$$d2025-02-27$$eAPC$$jStorniert$$lSpringerNature$$zDFG OAPK (Projekt) verrechnet durch V3
000623850 8767_ $$92025-02-27$$d2025-02-27$$eAPC$$jZahlung erfolgt$$lSpringerNature$$zDFG OAPK (Projekt) verrechnet durch V3
000623850 909CO $$ooai:bib-pubdb1.desy.de:623850$$pdnbdelivery$$popenCost$$pec_fundedresources$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1084564$$aDeutsches Elektronen-Synchrotron$$b0$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1084564$$aExternal Institute$$b0$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1084564$$aEuropean XFEL$$b0$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1095450$$aExternal Institute$$b2$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1095450$$aEuropean XFEL$$b2$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1099016$$aExternal Institute$$b3$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1099016$$aEuropean XFEL$$b3$$kXFEL.EU
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1014282$$aEuropean XFEL$$b4$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1103529$$aExternal Institute$$b5$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1103529$$aEuropean XFEL$$b5$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1027431$$aDeutsches Elektronen-Synchrotron$$b6$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1027431$$aExternal Institute$$b6$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1027431$$aEuropean XFEL$$b6$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1104549$$aExternal Institute$$b7$$kExtern
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1005343$$aDeutsches Elektronen-Synchrotron$$b8$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1099247$$aExternal Institute$$b9$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1099247$$aEuropean XFEL$$b9$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1007017$$aDeutsches Elektronen-Synchrotron$$b10$$kDESY
000623850 9101_ $$0I:(DE-H253)_CFEL-20120731$$6P:(DE-H253)PIP1007017$$aCentre for Free-Electron Laser Science$$b10$$kCFEL
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1007017$$aEuropean XFEL$$b10$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1031944$$aExternal Institute$$b11$$kExtern
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1014655$$aExternal Institute$$b12$$kExtern
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1099018$$aExternal Institute$$b13$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1099018$$aEuropean XFEL$$b13$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1087484$$aDeutsches Elektronen-Synchrotron$$b15$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1087484$$aExternal Institute$$b15$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1013759$$aEuropean XFEL$$b16$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1013728$$aDeutsches Elektronen-Synchrotron$$b17$$kDESY
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1013728$$aEuropean XFEL$$b17$$kXFEL.EU
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1014906$$aEuropean XFEL$$b18$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1027397$$aDeutsches Elektronen-Synchrotron$$b19$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1027397$$aExternal Institute$$b19$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1027397$$aEuropean XFEL$$b19$$kXFEL.EU
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1017364$$aEuropean XFEL$$b20$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1017364$$aExternal Institute$$b20$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1013098$$aEuropean XFEL$$b22$$kXFEL.EU
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1096868$$aEuropean XFEL$$b23$$kXFEL.EU
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1096868$$aExternal Institute$$b23$$kExtern
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1006803$$aExternal Institute$$b24$$kExtern
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1007320$$aExternal Institute$$b25$$kExtern
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1103428$$aExternal Institute$$b27$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1103428$$aEuropean XFEL$$b27$$kXFEL.EU
000623850 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-H253)PIP1084094$$aDeutsches Elektronen-Synchrotron$$b28$$kDESY
000623850 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1084094$$aExternal Institute$$b28$$kExtern
000623850 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1084094$$aEuropean XFEL$$b28$$kXFEL.EU
000623850 9131_ $$0G:(DE-HGF)POF4-631$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vMatter – Dynamics, Mechanisms and Control$$x0
000623850 9131_ $$0G:(DE-HGF)POF4-6G2$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vFLASH (DESY)$$x1
000623850 9141_ $$y2025
000623850 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)1050$$2StatID$$aDBCoverage$$bBIOSIS Previews$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)1190$$2StatID$$aDBCoverage$$bBiological Abstracts$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000623850 915__ $$0StatID:(DE-HGF)1040$$2StatID$$aDBCoverage$$bZoological Record$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bNAT COMMUN : 2022$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bNAT COMMUN : 2022$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2024-01-30T07:48:07Z
000623850 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2024-01-30T07:48:07Z
000623850 915__ $$0StatID:(DE-HGF)1030$$2StatID$$aDBCoverage$$bCurrent Contents - Life Sciences$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2025-01-02
000623850 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000623850 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Peer review$$d2024-01-30T07:48:07Z
000623850 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)1060$$2StatID$$aDBCoverage$$bCurrent Contents - Agriculture, Biology and Environmental Sciences$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2025-01-02
000623850 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2025-01-02
000623850 915pc $$0PC:(DE-HGF)0000$$2APC$$aAPC keys set
000623850 915pc $$0PC:(DE-HGF)0001$$2APC$$aLocal Funding
000623850 915pc $$0PC:(DE-HGF)0002$$2APC$$aDFG OA Publikationskosten
000623850 915pc $$0PC:(DE-HGF)0003$$2APC$$aDOAJ Journal
000623850 915pc $$0PC:(DE-HGF)0113$$2APC$$aDEAL: Springer Nature 2020
000623850 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x0
000623850 9201_ $$0I:(DE-H253)FS-FLASH-20140814$$kFS-FLASH$$lFS-FLASH$$x1
000623850 9201_ $$0I:(DE-H253)XFEL_E2_SQS-20210408$$kXFEL_E2_SQS$$lSQS$$x2
000623850 9201_ $$0I:(DE-H253)FS-FLASH-O-20160930$$kFS-FLASH-O$$lFLASH Wissenschaftlicher Nutzerbetrieb$$x3
000623850 9201_ $$0I:(DE-H253)FS-PETRA-S-20210408$$kFS-PETRA-S$$lPETRA-S$$x4
000623850 980__ $$ajournal
000623850 980__ $$aVDB
000623850 980__ $$aUNRESTRICTED
000623850 980__ $$aI:(DE-H253)HAS-User-20120731
000623850 980__ $$aI:(DE-H253)FS-FLASH-20140814
000623850 980__ $$aI:(DE-H253)XFEL_E2_SQS-20210408
000623850 980__ $$aI:(DE-H253)FS-FLASH-O-20160930
000623850 980__ $$aI:(DE-H253)FS-PETRA-S-20210408
000623850 980__ $$aAPC
000623850 9801_ $$aAPC
000623850 9801_ $$aFullTexts