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@ARTICLE{Kasneryk:623694,
      author       = {Kasneryk, Valeryia and Gazenbiller, Eugen and Wieland, D.
                      C. Florian and Garamus, Vasil M. and Serdechnova, Maria and
                      Blawert, Carsten and Zheludkevich, Mikhail L.},
      title        = {{F}rom {Z}n-{A}l {LDH} to {ZIF}-8@{Z}n-{A}l {LDH}
                      conversion coatings on the surface of {AA}2024 alloy:
                      {I}nside the process and the effect of the transformation on
                      the protective properties},
      journal      = {Surfaces and Interfaces},
      volume       = {59},
      issn         = {2468-0230},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {PUBDB-2025-00741},
      pages        = {105958},
      year         = {2025},
      abstract     = {Nowadays, interest in metal organic frameworks (MOFs) as
                      potential materials for corrosion protection of aluminium
                      alloys is increasing. However, application of MOFs in the
                      form of conversion coatings remains limited due to
                      challenging process of MOFs growth directly on Al based
                      surfaces. This obstacle can be overcome by surface
                      pretreatment that promotes further MOF formation. In the
                      current investigation, Zn-Al LDH (layered double hydroxide)
                      grown on the surface of AA2024 aluminium alloy was
                      recrystallised into ZIF-8@Zn-Al LDH coating. In situ
                      synchrotron and ex situ XRD analyses showed that
                      recrystallisation of Zn-Al LDH into ZIF-8 was accompanied by
                      intercalation of 2-methylimidazolate into the LDH gallery
                      under the applied treatment conditions. Such a complex
                      structure of the coating was beneficial for the corrosion
                      protection of AA2024 alloy as the obtained coating contained
                      an increased amount of 2-methylimidazole inhibitive species.
                      Moreover, it was found that the variation of the treatment
                      condition (95–140 °C, 3–24 h) affected the final
                      performance of the ZIF-8@Zn-Al-LDH coating and the coating
                      obtained at 95 °C for 12 h demonstrated the best
                      performance.},
      cin          = {DOOR ; HAS-User / Hereon},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)Hereon-20210428},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20211324
                      (I-20211324)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20211324},
      experiment   = {EXP:(DE-H253)P-P08-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:001424671400001},
      doi          = {10.1016/j.surfin.2025.105958},
      url          = {https://bib-pubdb1.desy.de/record/623694},
}