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000623168 1001_ $$0P:(DE-H253)PIP1103001$$aChauhan, Avantika$$b0
000623168 245__ $$aA comprehensive study on $H_2$ loading/deloading with PdAg alloy thin films using in-situ synchrotron radiation X-ray diffraction
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000623168 520__ $$aThe present study gives a comprehensive picture of interaction of hydrogen with Pd$_{0.54}$Ag$_{0.46}$ and Pd$_{0.88}$Ag$_{0.12}$ alloy thin films, at RT, 50 °C, 100 °C, 150 °C and200 °C, based on the experiments reported in the present work. During hydrogenation, the diffraction peaks shifted towards a lower angle, indicating an expansion of the lattice due to hydrogen incorporation revealed by in-situ synchrotron XRD. The cycles of hydrogen absorption and desorption were fully reversible, and no hysteresis was observed in the synthesized films. Our experiments suggest that at room temperature the magnitude of peak-shift on hydrogenation is larger with lower concentrations of Ag in Pd. Additionally, the interaction of PdAg alloy with hydrogen was observed to be temperature dependent. Increased hydrogenation temperature reduces the hydrogen sticking coefficient, reducing the peak shift magnitude for both samples. Additionally, at higher temperatures, hydrogen absorption is higher in Pd54Ag46 having smaller crystallite sizes than in Pd88Ag12.
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000623168 7001_ $$0P:(DE-H253)PIP1020660$$aDey, Arka Bikash$$b1
000623168 7001_ $$0P:(DE-H253)PIP1007852$$aBertram, Florian$$b2
000623168 7001_ $$aChawla, Vipin$$b3
000623168 7001_ $$0P:(DE-H253)PIP1015097$$aGupta, Mukul$$b4
000623168 7001_ $$aRao, Akula Umamaheswara$$b5
000623168 7001_ $$0P:(DE-H253)PIP1103091$$aMishra, Yogendra Kumar$$b6
000623168 7001_ $$0P:(DE-H253)PIP1097891$$aChawla, Amit Kumar$$b7$$eCorresponding author
000623168 7001_ $$0P:(DE-H253)PIP1015276$$aAvasthi, Devesh Kumar$$b8$$eCorresponding author
000623168 773__ $$0PERI:(DE-600)2829441-5$$a10.1016/j.mtcomm.2024.111079$$gVol. 41, p. 111079 -$$p111079 $$tMaterials today / Communications$$v41$$x2352-4928$$y2024
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000623168 8564_ $$uhttps://bib-pubdb1.desy.de/record/623168/files/document.pdf$$yPublished on 2024-12-01. Available in OpenAccess from 2025-12-01.
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