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@ARTICLE{Bachmann:622926,
author = {Bachmann, Lydia Johanna and Lapkin, Dmitrii and Schober,
Jan-Christian and Dolling, Silvan and Kim, Young Yong and
Assalauova, Dameli and Mukharamova, Nastasia and Dwivedi,
Jagrati and Schulli, Tobias and Keller, Thomas F. and
Vartaniants, Ivan and Stierle, Andreas},
title = {{C}oherent {X}-ray {D}iffraction {I}maging of a {T}winned
{P}t{R}h {C}atalyst {N}anoparticle under {O}perando
{C}onditions},
journal = {ACS nano},
volume = {19},
number = {26},
issn = {1936-0851},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PUBDB-2025-00562},
pages = {23552 - 23563},
year = {2025},
abstract = {We performed operando Bragg coherent X-ray diffraction
imaging under CO oxidation,as well as oxidizing conditions
on a pre-characterized single PtRh nanoparticleand found
that this (111) oriented particle with truncated octahedral
shape is twinnedwith a Σ3 twin boundary parallel to the
SrTiO3 (001) support, at the height of thenanoparticle
edges. We observed that the average strain at the twin
boundary is higherunder CO oxidation conditions compared to
pure CO or O2. In addition, we observedthat two new facets
were forming during the oxidizing/reducing cycles.
Furthermore,we found mixed edge/screw dislocations at the
twin boundary, but only where the{111} side facets meet.
Inducing such dislocations changes the local strain and
theatomic structure of the nanoparticles, which may create
more active sites close to thenanoparticle edges.},
cin = {FS-NL / FS-PS},
ddc = {540},
cid = {I:(DE-H253)FS-NL-20120731 / I:(DE-H253)FS-PS-20131107},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / SFB 1441 A05 - Struktur und
Zusammensetzung von PtPd Modellkatalysatoren unter operando
Bedingungen: Experiment und Theorie (A05) (446698573) / NEP
- Nanoscience Foundries and Fine Analysis - Europe|PILOT
(101007417)},
pid = {G:(DE-HGF)POF4-632 / G:(GEPRIS)446698573 /
G:(EU-Grant)101007417},
experiment = {EXP:(DE-H253)Nanolab-04-20150101 /
EXP:(DE-H253)Nanolab-01-20150101 /
EXP:(DE-H253)Nanolab-03-20150101 /
EXP:(DE-MLZ)External-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:40559514},
doi = {10.1021/acsnano.4c15457},
url = {https://bib-pubdb1.desy.de/record/622926},
}