Home > Publications database > Monitoring the Fate of Zn in the Cu/ZnO/ZrO$_2$ Catalyst during CO$_2$‐to‐Methanol Synthesis at High Conversions by Operando Spectroscopy > print

001     622772
005     20250723105719.0
024 7 _ |a 10.1002/anie.202423281
|2 doi
024 7 _ |a 1433-7851
|2 ISSN
024 7 _ |a 0570-0833
|2 ISSN
024 7 _ |a 1521-3773
|2 ISSN
024 7 _ |a 10.3204/PUBDB-2025-00466
|2 datacite_doi
024 7 _ |a altmetric:174247679
|2 altmetric
024 7 _ |a pmid:39866096
|2 pmid
024 7 _ |a WOS:001421758200001
|2 WOS
024 7 _ |a openalex:W4406847171
|2 openalex
037 _ _ |a PUBDB-2025-00466
041 _ _ |a English
082 _ _ |a 540
100 1 _ |a Schulte, Mariam L.
|0 P:(DE-H253)PIP1093119
|b 0
245 _ _ |a Monitoring the Fate of Zn in the Cu/ZnO/ZrO$_2$ Catalyst during CO$_2$‐to‐Methanol Synthesis at High Conversions by Operando Spectroscopy
260 _ _ |a Weinheim
|c 2025
|b Wiley-VCH
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1744196809_2962106
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
500 _ _ |a Supposed to be Open Access covered by Project Deal (after corresponding author signs the publishing agreement).
520 _ _ |a In the frame of developing a sustainable chemical industry, heterogeneously catalyzed CO$_2$ hydrogenation to methanol has attracted considerable interest. However, the Cu-Zn based catalyst system employed in this process is very dynamic, especially in the presence of the products methanol and water. Deactivation needs to be prevented, but its origin and mechanism are hardly investigated at high conversion where product condensation is possible. Here, we report on the structural dynamics of a Cu/ZnO/ZrO$_2$ catalyst at 90 bar and 40% CO$_2$ conversion (at equilibrium conditions), investigated in a dedicated metal-based spectroscopic cell specially fabricated using additive manufacturing. This particular reactor configuration aims to mimic the high CO$_2$ conversion part of the catalyst bed and can induce product condensation, which is monitored by operando X-ray absorption spectroscopy. While Cu remained mostly stable throughout the experiment, Zn underwent strong restructuring. The chosen reaction conditions, including the use of CO$_2$ as carbon source and in situ product condensation, were selected to provide insights under industrial conditions. This work highlights the importance of spectroscopic investigations at high conversion levels, offering insights into chemical transformations during deactivation, extending the concept of spatially resolved studies, and thus providing guidance for the design of more stable catalysts.
536 _ _ |a 6G3 - PETRA III (DESY) (POF4-6G3)
|0 G:(DE-HGF)POF4-6G3
|c POF4-6G3
|f POF IV
|x 0
536 _ _ |a FS-Proposal: I-20230260 (I-20230260)
|0 G:(DE-H253)I-20230260
|c I-20230260
|x 1
536 _ _ |a DFG project G:(GEPRIS)460248799 - DAPHNE4NFDI - DAten aus PHoton- und Neutronen Experimenten für NFDI (460248799)
|0 G:(GEPRIS)460248799
|c 460248799
|x 2
588 _ _ |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de
693 _ _ |a PETRA III
|f PETRA Beamline P65
|1 EXP:(DE-H253)PETRAIII-20150101
|0 EXP:(DE-H253)P-P65-20150101
|6 EXP:(DE-H253)P-P65-20150101
|x 0
700 1 _ |a Truttmann, Vera
|0 P:(DE-H253)PIP1105191
|b 1
700 1 _ |a Doronkin, Dmitry E.
|0 P:(DE-H253)PIP1017208
|b 2
700 1 _ |a Baumgarten, Lorena
|0 P:(DE-H253)PIP1100120
|b 3
700 1 _ |a Nicolai, Alexander
|0 P:(DE-H253)PIP1107811
|b 4
700 1 _ |a Beltran, Diego Alejandro Montalvo
|b 5
700 1 _ |a Summ, Florian J.
|b 6
700 1 _ |a Kiener, Christoph
|b 7
700 1 _ |a Warmuth, Lucas
|b 8
700 1 _ |a Pitter, Stephan
|b 9
700 1 _ |a Saraçi, Erisa
|0 P:(DE-H253)PIP1097957
|b 10
700 1 _ |a Grunwaldt, Jan-Dierk
|0 P:(DE-H253)PIP1008522
|b 11
|e Corresponding author
773 _ _ |a 10.1002/anie.202423281
|g p. e202423281
|0 PERI:(DE-600)2011836-3
|n 15
|p e202423281
|t Angewandte Chemie / International edition
|v 64
|y 2025
|x 1433-7851
856 4 _ |u https://bib-pubdb1.desy.de/record/622772/files/Angew%20Chem%20Int%20Ed%20-%202025%20-%20Schulte%20-%20Monitoring%20the%20Fate%20of%20Zn%20in%20the%20Cu%20ZnO%20ZrO2%20Catalyst%20During%20CO2%E2%80%90to%E2%80%90Methanol%20Synthesis.pdf
|y OpenAccess
856 4 _ |u https://bib-pubdb1.desy.de/record/622772/files/Angew%20Chem%20Int%20Ed%20-%202025%20-%20Schulte%20-%20Monitoring%20the%20Fate%20of%20Zn%20in%20the%20Cu%20ZnO%20ZrO2%20Catalyst%20During%20CO2%E2%80%90to%E2%80%90Methanol%20Synthesis.pdf?subformat=pdfa
|x pdfa
|y OpenAccess
909 C O |o oai:bib-pubdb1.desy.de:622772
|p openaire
|p open_access
|p VDB
|p driver
|p dnbdelivery
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 0
|6 P:(DE-H253)PIP1093119
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 1
|6 P:(DE-H253)PIP1105191
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 2
|6 P:(DE-H253)PIP1017208
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 3
|6 P:(DE-H253)PIP1100120
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 4
|6 P:(DE-H253)PIP1107811
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 10
|6 P:(DE-H253)PIP1097957
910 1 _ |a External Institute
|0 I:(DE-HGF)0
|k Extern
|b 11
|6 P:(DE-H253)PIP1008522
913 1 _ |a DE-HGF
|b Forschungsbereich Materie
|l Großgeräte: Materie
|1 G:(DE-HGF)POF4-6G0
|0 G:(DE-HGF)POF4-6G3
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-600
|4 G:(DE-HGF)POF
|v PETRA III (DESY)
|x 0
914 1 _ |y 2025
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0160
|2 StatID
|b Essential Science Indicators
|d 2024-12-16
915 _ _ |a Creative Commons Attribution CC BY 4.0
|0 LIC:(DE-HGF)CCBY4
|2 HGFVOC
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0600
|2 StatID
|b Ebsco Academic Search
|d 2024-12-16
915 _ _ |a IF >= 15
|0 StatID:(DE-HGF)9915
|2 StatID
|b ANGEW CHEM INT EDIT : 2022
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
|d 2024-12-16
915 _ _ |a DEAL Wiley
|0 StatID:(DE-HGF)3001
|2 StatID
|d 2024-12-16
|w ger
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1030
|2 StatID
|b Current Contents - Life Sciences
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1210
|2 StatID
|b Index Chemicus
|d 2024-12-16
915 _ _ |a WoS
|0 StatID:(DE-HGF)0113
|2 StatID
|b Science Citation Index Expanded
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
|d 2024-12-16
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a Peer Review
|0 StatID:(DE-HGF)0030
|2 StatID
|b ASC
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1200
|2 StatID
|b Chemical Reactions
|d 2024-12-16
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b ANGEW CHEM INT EDIT : 2022
|d 2024-12-16
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
|d 2024-12-16
915 _ _ |a Nationallizenz
|0 StatID:(DE-HGF)0420
|2 StatID
|d 2024-12-16
|w ger
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
|d 2024-12-16
920 1 _ |0 I:(DE-H253)FS_DOOR-User-20241023
|k FS DOOR-User
|l FS DOOR-User
|x 0
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a I:(DE-H253)FS_DOOR-User-20241023
980 _ _ |a UNRESTRICTED
980 1 _ |a FullTexts

LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21