TY  - JOUR
AU  - Schulte, Mariam L.
AU  - Truttmann, Vera
AU  - Doronkin, Dmitry E.
AU  - Baumgarten, Lorena
AU  - Nicolai, Alexander
AU  - Beltran, Diego Alejandro Montalvo
AU  - Summ, Florian J.
AU  - Kiener, Christoph
AU  - Warmuth, Lucas
AU  - Pitter, Stephan
AU  - Saraçi, Erisa
AU  - Grunwaldt, Jan-Dierk
TI  - Monitoring the Fate of Zn in the Cu/ZnO/ZrO<sub>2</sub> Catalyst during CO<sub>2</sub>‐to‐Methanol Synthesis at High Conversions by Operando Spectroscopy
JO  - Angewandte Chemie / International edition
VL  - 64
IS  - 15
SN  - 1433-7851
CY  - Weinheim
PB  - Wiley-VCH
M1  - PUBDB-2025-00466
SP  - e202423281
PY  - 2025
N1  - Supposed to be Open Access covered by Project Deal (after corresponding author signs the publishing agreement).
AB  - In the frame of developing a sustainable chemical industry, heterogeneously catalyzed CO<sub>2</sub> hydrogenation to methanol has attracted considerable interest. However, the Cu-Zn based catalyst system employed in this process is very dynamic, especially in the presence of the products methanol and water. Deactivation needs to be prevented, but its origin and mechanism are hardly investigated at high conversion where product condensation is possible. Here, we report on the structural dynamics of a Cu/ZnO/ZrO<sub>2</sub> catalyst at 90 bar and 40
LB  - PUB:(DE-HGF)16
C6  - pmid:39866096
UR  - <Go to ISI:>//WOS:001421758200001
DO  - DOI:10.1002/anie.202423281
UR  - https://bib-pubdb1.desy.de/record/622772
ER  -