%0 Journal Article
%A Schulte, Mariam L.
%A Truttmann, Vera
%A Doronkin, Dmitry E.
%A Baumgarten, Lorena
%A Nicolai, Alexander
%A Beltran, Diego Alejandro Montalvo
%A Summ, Florian J.
%A Kiener, Christoph
%A Warmuth, Lucas
%A Pitter, Stephan
%A Saraçi, Erisa
%A Grunwaldt, Jan-Dierk
%T Monitoring the Fate of Zn in the Cu/ZnO/ZrO<sub>2</sub> Catalyst during CO<sub>2</sub>‐to‐Methanol Synthesis at High Conversions by Operando Spectroscopy
%J Angewandte Chemie / International edition
%V 64
%N 15
%@ 1433-7851
%C Weinheim
%I Wiley-VCH
%M PUBDB-2025-00466
%P e202423281
%D 2025
%Z Supposed to be Open Access covered by Project Deal (after corresponding author signs the publishing agreement).
%X In the frame of developing a sustainable chemical industry, heterogeneously catalyzed CO<sub>2</sub> hydrogenation to methanol has attracted considerable interest. However, the Cu-Zn based catalyst system employed in this process is very dynamic, especially in the presence of the products methanol and water. Deactivation needs to be prevented, but its origin and mechanism are hardly investigated at high conversion where product condensation is possible. Here, we report on the structural dynamics of a Cu/ZnO/ZrO<sub>2</sub> catalyst at 90 bar and 40
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:39866096
%U <Go to ISI:>//WOS:001421758200001
%R 10.1002/anie.202423281
%U https://bib-pubdb1.desy.de/record/622772