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@ARTICLE{Luo:622593,
      author       = {Luo, Tian and Jeppesen, Henrik S. and Schoekel, Alexander
                      and Bönisch, Nadine and Xu, Fei and Zhuang, Rong and Huang,
                      Qiang and Senkovska, Irena and Bon, Volodymyr and Heine,
                      Thomas and Kuc, Agnieszka and Kaskel, Stefan},
      title        = {{P}hotocatalytic {D}ehalogenation of {A}ryl {H}alides
                      {M}ediated by the {F}lexible {M}etal–{O}rganic {F}ramework
                      {MIL}‐53({C}r)},
      journal      = {Angewandte Chemie / International edition},
      volume       = {64},
      number       = {13},
      issn         = {1433-7851},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2025-00406},
      pages        = {e202422776},
      year         = {2025},
      abstract     = {The catalytic potential of flexible metal–organic
                      frameworks (MOFs) remains underexplored, particularly in
                      liquid-phase reactions. This study employs MIL-53(Cr), a
                      prototypical “breathing” MOF capable of structural
                      adaptation via pore size modulation, as a photocatalyst for
                      the dehalogenation of aryl halides. Powder X-ray diffraction
                      and Pair Distribution Function analyses reveal that organic
                      solvents influence pore opening, while substrates and
                      products dynamically adjust the framework configuration
                      during catalysis. This structural flexibility enables
                      precise tuning of photocatalytic efficiency via
                      solvent-mediated control of the pore aperture. The results
                      demonstrate that the dynamic behavior of MIL-53(Cr)
                      facilitates enhanced catalytic activity and selectivity,
                      advancing the application of flexible MOFs as tunable,
                      enzyme-mimicking catalysts. These findings pave the way for
                      the rational design of next-generation flexible
                      photocatalysts.},
      cin          = {DOOR ; HAS-User / FS-PET-D},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PET-D-20190712},
      pnm          = {631 - Matter – Dynamics, Mechanisms and Control
                      (POF4-631) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      FS-Proposal: I-20220986 (I-20220986)},
      pid          = {G:(DE-HGF)POF4-631 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-H253)I-20220986},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39744930},
      UT           = {WOS:001396027200001},
      doi          = {10.1002/anie.202422776},
      url          = {https://bib-pubdb1.desy.de/record/622593},
}