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@ARTICLE{Peng:622465,
author = {Peng, Jun and Brandt, Julia and Pfeiffer, Maurice and G.
Maragno, Laura and Krekeler, Tobias and T. James, Nithin and
Henf, Julius and Heyn, Christian and Ritter, Martin and
Eich, Manfred and Petrov, Alexander Yu. and P. Furlan,
Kaline and Blick, Robert and Zierold, Robert},
title = {{S}witchable 3{D} {P}hotonic {C}rystals {B}ased on the
{I}nsulator-to-{M}etal {T}ransition in {VO}$_2$},
journal = {ACS applied materials $\&$ interfaces},
volume = {16},
number = {49},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PUBDB-2025-00328},
pages = {67106-67115},
year = {2024},
abstract = {Photonic crystals (PhCs) are optical structures
characterized by the spatial modulation of the dielectric
function, which results in the formation of a photonic band
gap (PBG) in the frequency spectrum. This PBG blocks the
propagation of light, enabling filtering, confinement, and
manipulation of light. Most of the research in this field
has concentrated on static PhCs, which have fixed structural
and material parameters, leading to a constant PBG. However,
the growing demand for adaptive photonic devices has led to
an increased interest in switchable PhCs, where the PBG can
be reversibly activated or shifted. Vanadium dioxide (VO2)
is particularly notable for its near-room-temperature
insulator-to-metal transition (IMT), which is accompanied by
significant changes in its optical properties. Here, we
demonstrate a fabrication strategy for switchable
three-dimensional (3D) PhCs, involving sacrificial templates
and a VO2 atomic layer deposition (ALD) process in
combination with an accurately controlled annealing
procedure. The resulting VO2 inverse opal (IO) PhC achieves
substantial control over PBG in the near-infrared (NIR)
region. Specifically, the synthesized VO$_2$ IO PhC exhibits
PBGs near 1.49 and 1.03 μm in the dielectric and metallic
states of the VO$_2$ material, respectively, which can be
reversibly switched by adjusting the external temperature.
Furthermore, a temperature-dependent switch from a
narrow-band NIR reflector to a broad-band absorber is
revealed. This work highlights the potential of integrating
VO$_2$ into 3D templates in the development of switchable
photonics with complex 3D structures, offering a promising
avenue for the advancement of photonic devices with
adaptable functionalities.},
cin = {FS-PS},
ddc = {600},
cid = {I:(DE-H253)FS-PS-20131107},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / DFG project G:(GEPRIS)192346071 - SFB
986: Maßgeschneiderte Multiskalige Materialsysteme - M3
(192346071)},
pid = {G:(DE-HGF)POF4-632 / G:(GEPRIS)192346071},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {39622080},
UT = {WOS:001368389400001},
doi = {10.1021/acsami.4c13789},
url = {https://bib-pubdb1.desy.de/record/622465},
}