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@ARTICLE{Hayen:622275,
author = {Hayen, Nicolas and Jordt, Philipp and Hoevelmann, Svenja
Carolin and Petersdorf, Lukas and Mewes, Mathis and
Thormählen, Lars and Meyners, Dirk and Sun, Nian X. and
Sternemann, Christian and Paulus, Michael and
Lützenkirchen-Hecht, Dirk and Murphy, Bridget},
title = {{I}n {S}itu {X}‐{R}ay {A}bsorption {S}tudies on {L}ocal
{S}tructure of {A}nnealed {M}etallic {G}lasses {F}e{G}a{B}
and {F}e{C}o{S}i{B}},
journal = {Physica status solidi / A},
volume = {222},
number = {14},
issn = {1862-6300},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {PUBDB-2025-00313},
pages = {2400607},
year = {2025},
abstract = {The microscopic structure of Fe-based metallic glasses
(FeGaB) and (FeCoSiB) is investigated during in situ thermal
annealing using extended X-ray absorption fine structure
spectroscopy (EXAFS) above the Fe–K and Co–K absorption
edges. FeGaB exhibits a phase transition above 450 °C,
changing from amorphous glass to a partially crystalline
structure. Its medium-range structure after this transition
is modeled from crystalline α-Fe and reference structures,
combined with amorphous nearest-neighbor (NN) contributions
of . Local order in the glass phase is described with the
same model, restricted to NN interactions. Changes in the
amorphous structure occur at annealing temperatures which
coincide with typical observations of changes in magnetic
behavior. Meanwhile, in FeCoSiB, the EXAFS response is
highly different between the Fe–K and Co–K absorption
edges. EXAFS oscillations on the Fe edge are strongly
suppressed, as opposed to the Co edge which shows typical
amplitudes. Limited resolution in this data set allows
modeling only in the first amorphous shell, based on the NN
distances from FeCo. The cause of the two materials’
different EXAFS behavior at Fe–K despite similar iron
content and identical experimental conditions is currently
unknown and subject of further investigation.},
cin = {FS-SXQM},
ddc = {530},
cid = {I:(DE-H253)FS-SXQM-20190201},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / DFG project G:(GEPRIS)460248799 -
DAPHNE4NFDI - DAten aus PHoton- und Neutronen Experimenten
für NFDI (460248799) / DFG project G:(GEPRIS)286471992 -
SFB 1261: Magnetoelektrische Sensoren: von
Kompositmaterialien zu biomagnetischer Diagnose (286471992)},
pid = {G:(DE-HGF)POF4-632 / G:(GEPRIS)460248799 /
G:(GEPRIS)286471992},
experiment = {EXP:(DE-MLZ)External-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:001360420600001},
doi = {10.1002/pssa.202400607},
url = {https://bib-pubdb1.desy.de/record/622275},
}